Highly diastereoselective and enantioselective addition of organometallic reagents to a chiral c-2-symmetrical bisimine
文献类型：期刊论文
| 作者 | Sun, XX; Wan, SJ; Sun, SJ; Zhu, J; Deng, JG |
| 刊名 | Synlett
 |
| 出版日期 | 2005-11-03 |
| 期号 | 18页码:2776-2780 |
| 关键词 | Chiral 1,2-diamine Chiral bisimine Asymmetric addition Organometallic reagents Asymmetric allylation |
| ISSN号 | 0936-5214 |
| DOI | 10.1055/s-2005-918927 |
| 通讯作者 | Deng, jg() |
| 英文摘要 | An efficient and straightforward method has been developed for the preparation of enantiomerically enriched c-2-symmetrical vicinal diamines via the addition of organometallic reagents to a chiral bisimine, which gives access to a variety of optically pure aromatic and aliphatic c-2-symmetrical vicinal diamines in high yields. the 'cram-davis' open transition state model is proposed to rationalize the observed stereoselectivities for the addition of organolithium reagents to the bisimine. |
| WOS关键词 | TERT-BUTANESULFINYL IMINES ; ASYMMETRIC-SYNTHESIS ; STEREOSELECTIVE-SYNTHESIS ; EFFICIENT SYNTHESIS ; VICINAL DIAMINES ; HYDROGENATION ; AMINES ; 1,2-DIAMINE ; ALDIMINES ; COMPLEXES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000233175500015 |
| 出版者 | GEORG THIEME VERLAG KG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377292 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Deng, JG |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, XX,Wan, SJ,Sun, SJ,et al. Highly diastereoselective and enantioselective addition of organometallic reagents to a chiral c-2-symmetrical bisimine[J]. Synlett,2005(18):2776-2780. |
| APA | Sun, XX,Wan, SJ,Sun, SJ,Zhu, J,&Deng, JG.(2005).Highly diastereoselective and enantioselective addition of organometallic reagents to a chiral c-2-symmetrical bisimine.Synlett(18),2776-2780. |
| MLA | Sun, XX,et al."Highly diastereoselective and enantioselective addition of organometallic reagents to a chiral c-2-symmetrical bisimine".Synlett .18(2005):2776-2780. |
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来源：中国科学院大学
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