An ionic liquid-type carbon paste polyoxometalate-modified electrode and its properties
文献类型：期刊论文
| 作者 | Liu, HT; He, P; Li, ZY; Sun, CY; Shi, LH; Liu, Y; Zhu, GY; Li, JH |
| 刊名 | Electrochemistry communications
 |
| 出版日期 | 2005-12-01 |
| 卷号 | 7期号:12页码:1357-1363 |
| 关键词 | Carbon paste electrode Ionic liquid Bulk-modified Polyoxomolybdate Electrocatalytic activity |
| ISSN号 | 1388-2481 |
| DOI | 10.1016/j.elecom.2005.09.018 |
| 通讯作者 | Li, jh(jhli@mail.tsinghua.edu.cn) |
| 英文摘要 | The replacement of a non-conductive organic binder with a conductive room temperature ionic liquid in fabricating carbon paste electrode has been made. this new electrode due to its enhanced conductivity presented very large current response from electroactive substrates. the novel carbon paste electrode was bulk-modified via the uniform dispersion of keggin-type phospho polyoxomolybdate pmo12o403- (pmo12) in bulky carbons, which possessed excellent electrocatalytic activity for the reduction of nitrite. the pronounced multi-electron catalytic ability was ascribed to the used hydrophobic ionic liquid which constructed an excellent charge-transfer bridge in the bulk of carbon paste electrode, thus facilitated the intake of electrons from reduced pmo12 mediators. in view of their prominent properties, the carbon paste electrode using ionic liquid binder and its bulk-modified electrode take on good prospects of the application in physical chemistry and electroanalytical chemistry fields. (c) 2005 elsevier b.v. all rights reserved. |
| WOS关键词 | REDUCTION ; SOLVENT ; SENSORS ; 12-MOLYBDOPHOSPHATE ; 12-MOLYBDOSILICATE ; VOLTAMMETRY ; CHEMISTRY ; SURFACE ; CATION ; ANION |
| WOS研究方向 | Electrochemistry |
| WOS类目 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000233720500031 |
| 出版者 | ELSEVIER SCIENCE INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377338 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, JH |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, HT,He, P,Li, ZY,et al. An ionic liquid-type carbon paste polyoxometalate-modified electrode and its properties[J]. Electrochemistry communications,2005,7(12):1357-1363. |
| APA | Liu, HT.,He, P.,Li, ZY.,Sun, CY.,Shi, LH.,...&Li, JH.(2005).An ionic liquid-type carbon paste polyoxometalate-modified electrode and its properties.Electrochemistry communications,7(12),1357-1363. |
| MLA | Liu, HT,et al."An ionic liquid-type carbon paste polyoxometalate-modified electrode and its properties".Electrochemistry communications 7.12(2005):1357-1363. |
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来源：中国科学院大学
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