Synthesis and crystal structure of dichlorobis-(1-methylimidazoline-2(3h)-thione-s) cobalt(iii)
文献类型：期刊论文
| 作者 | Wang, YL; Cao, R; Bi, WH |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2005 |
| 卷号 | 24期号:3页码:303-306 |
| 关键词 | Cobalt(ii) complex 1-methylimidazoline-2(3h)-thione Crystal structure Hydrogen bonding Pi-pi stacking interactions |
| ISSN号 | 0254-5861 |
| 通讯作者 | Cao, r() |
| 英文摘要 | The reaction of anhydrous cobalt(ii) dichloride with 1-methylimidazoline-2(3h)thione in dichloromethane solution gave the title complex, [co(c4h6n2s)(2)cl-2]. x-ray single-crystal analysis revealed that the complex crystallizes in a monoclinic system, space group p2(1)/c, a = 13.9707(10), b = 10.0435(7), c = 10.3910(6) angstrom, beta 91.181(3)degrees, v 1457.70(17) angstrom(3), z = 4, c8h12cl2n4s2co, m-r = 358.17, d-c = 1.632 g/cm(3), mu = 1.813 mm(-1), f(000) = 724, the final r 0.0710 and wr = 0.1224 for 1549 observed reflections with i > 2 sigma(i). the co atom is coordinated by two s atoms from two 1-methylimidazoline-2(3h)-thione ligands and two chloride ions in a slightly distorted tetrahedral geometry. the intramolecular classical hydrogen-bonding interactions involving chloride ions and n-h groups of the heterocyclic thione ligands are observed. the offset pi-pi stacking interactions between the imidazole rings of adjacent molecules with a face-to-face distance of 3.604 angstrom are found in the packing diagram. |
| WOS关键词 | ALCOHOL-DEHYDROGENASE ; COMPLEXES ; CD ; HG |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000227940900012 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377366 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao, R |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, YL,Cao, R,Bi, WH. Synthesis and crystal structure of dichlorobis-(1-methylimidazoline-2(3h)-thione-s) cobalt(iii)[J]. Chinese journal of structural chemistry,2005,24(3):303-306. |
| APA | Wang, YL,Cao, R,&Bi, WH.(2005).Synthesis and crystal structure of dichlorobis-(1-methylimidazoline-2(3h)-thione-s) cobalt(iii).Chinese journal of structural chemistry,24(3),303-306. |
| MLA | Wang, YL,et al."Synthesis and crystal structure of dichlorobis-(1-methylimidazoline-2(3h)-thione-s) cobalt(iii)".Chinese journal of structural chemistry 24.3(2005):303-306. |
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来源：中国科学院大学
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