Aerobic oxidation of benzyl alcohol by fe-system catalyst
文献类型：期刊论文
| 作者 | Xiong, YL; Xiao, DH; Li, J; Xie, XF; Yang, XG; Wu, Y |
| 刊名 | Zeitschrift fur physikalische chemie-international journal of research in physical chemistry & chemical physics
 |
| 出版日期 | 2005 |
| 卷号 | 219期号:8页码:1121-1131 |
| 关键词 | Benzyl alcohol Aerobic oxidation Activation of molecule oxygen Redox potential Electron state |
| ISSN号 | 0942-9352 |
| 通讯作者 | Yang, xg() |
| 英文摘要 | The catalytic oxidation of benzyl alcohol has been carried out by using dioxygen as oxidant in the presence of fe(acac)(3) (acetyl acetone)/1,10-phenanthroline/base system in toluene at 80 degrees. oxygen was activated successfully by the fe-catalyst and oxidized benzyl alcohol to benzyl aldehyde in similar to 100% selectivity. it was found that the oxidation of benzyl alcohol was very sensitive to water in this reaction system, and small amount of water could obviously decrease the reactivity. based on the results of cyclic voltammetry and esr, a binuclear-fe mechanism was also proposed. |
| WOS关键词 | HYDROGEN-PEROXIDE ; EFFICIENT |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000231361000005 |
| 出版者 | OLDENBOURG VERLAG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377380 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yang, XG |
| 作者单位 | Chinese Acad Sci, Grad Sch, Changchun Inst Appl Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, YL,Xiao, DH,Li, J,et al. Aerobic oxidation of benzyl alcohol by fe-system catalyst[J]. Zeitschrift fur physikalische chemie-international journal of research in physical chemistry & chemical physics,2005,219(8):1121-1131. |
| APA | Xiong, YL,Xiao, DH,Li, J,Xie, XF,Yang, XG,&Wu, Y.(2005).Aerobic oxidation of benzyl alcohol by fe-system catalyst.Zeitschrift fur physikalische chemie-international journal of research in physical chemistry & chemical physics,219(8),1121-1131. |
| MLA | Xiong, YL,et al."Aerobic oxidation of benzyl alcohol by fe-system catalyst".Zeitschrift fur physikalische chemie-international journal of research in physical chemistry & chemical physics 219.8(2005):1121-1131. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。