Synthesis and crystal structure of [la(btc)(h2o)(6)](n)
文献类型：期刊论文
| 作者 | Wen, YH; Cheng, JK; Feng, YL; Zhang, J; Li, ZJ; Yao, YG |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2005 |
| 卷号 | 24期号:12页码:1440-1444 |
| 关键词 | Hydrothermal reaction Ribbon-like Non-covalent interactions |
| ISSN号 | 0254-5861 |
| 通讯作者 | Yao, yg() |
| 英文摘要 | The title compound, [la(btc)(h2o)(6)](n) 1 (h3btc = benzene- 1,3,5-tricarboxylic acid), has been synthesized by the hydrothermal reaction of la(no3)(3)(.)3h(2)o with h3btc and na2co3, and its structure was determined by single-crystal x-ray diffraction. the crystal structure is of monoclinic, space group cc with a = 11.5289(3), b = 18.0383(7), c = 7.3507(3) angstrom, beta = 119.5680(10)degrees, v = 1.329.59(8) angstrom(3), c9h15lao12, m-r = 454.12, z = 4, d-c. = 2.269 g/cm(3), mu = 3.280 mm(-1), flack parameter = 0.07(4), f(000) = 888, r = 0.0316 and wr = 0.0774 for 1312 observed reflections(i > 2 alpha(i)). complex 1 features a one-dimensional (1-d) parallel ribbon-like structure. there are extensive hydrogen-bonding interactions involving coordinated water molecules and free carboxylate oxygen atoms. in addition, pi-pi interactions via benzoic multicarboxylate ligands are discussed. these non-covalent interactions lead to the formation of a 3-d framework. |
| WOS关键词 | COORDINATION POLYMER ; FRAMEWORK ; COMPLEXES ; NETWORK ; UNITS ; ACID ; NLO |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000234340400015 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377458 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yao, YG |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen, YH,Cheng, JK,Feng, YL,et al. Synthesis and crystal structure of [la(btc)(h2o)(6)](n)[J]. Chinese journal of structural chemistry,2005,24(12):1440-1444. |
| APA | Wen, YH,Cheng, JK,Feng, YL,Zhang, J,Li, ZJ,&Yao, YG.(2005).Synthesis and crystal structure of [la(btc)(h2o)(6)](n).Chinese journal of structural chemistry,24(12),1440-1444. |
| MLA | Wen, YH,et al."Synthesis and crystal structure of [la(btc)(h2o)(6)](n)".Chinese journal of structural chemistry 24.12(2005):1440-1444. |
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来源：中国科学院大学
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