Cadmium(ii) and cobalt(ii) complexes generated from benzimidazole-5-carboxylate: self-assembly by hydrogen bonding and pi-pi interactions
文献类型：期刊论文
| 作者 | Liu, Z; Chen, Y; Liu, P; Wang, J; Huang, MH |
| 刊名 | Journal of solid state chemistry
 |
| 出版日期 | 2005-07-01 |
| 卷号 | 178期号:7页码:2306-2312 |
| 关键词 | Cadmium(ii) Cobalt(ii) Pi pi interaction Hydrogen bonding interactions Channel Zigzag chain |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2005.04.037 |
| 通讯作者 | Liu, z(pliu@ms.fjirsm.ac.cn) |
| 英文摘要 | Self-assembly of l- (hl = benzimidazole-5-carboxylic acid) with cd(ii) and co(ii), respectively, by layer-separating diffusion method at ambient temperature gives rise to two new supramolecular architectures [((cdl2h2o)-h-.)(.)2ch(3)oh](n) (1) and {[col2(h2o)(2)](.)2h(2)o}(n) (2), both of which are stabilized by the hydrogen bonding interactions and the intermolecular pi-pi interactions. 1 crystallizes in the triclinic system, space group p-1. with cell parameters m=516.78, a=9.084(2)angstrom b = 10.063(10)angstrom c = 11.533(8)angstrom, x = 90.21(11), beta = 99.49(6). gamma = 98.34(9). gamma = 1028.4(12)angstrom, z = 2. r-1[i > 2 sigma(i)] = 0.0257, wr(2)[i > 2 sigma(i)] = 0.0719. 2 crystallizes in the monoclinic system. space group c2/(3)c with cell parameters m = 453.27, a = 16.119(2)angstrom, b = 8.8952(13)angstrom. c = 14.195(2) angstrom, beta = 118.507(2), gamma = 1788.5(4)angstrom. z = 4. r-1[i > 2 sigma(i)] = 0.0802, wr(2) [i > 2 sigma(i)] = 0.1515. complex 1 displays a remarkable three-dimensional (3-d) structure with unusual channels' generated from the interlayer voids. complex 2 exhibits the 3-d structure consisting of 1-d zigzag chains. the thermal and fluorescence properties associated with their crystal structures have been measured. and complex 1 displays intense blue emission in the solid state. (c) 2005 elsevier inc. all rights reserved. |
| WOS关键词 | TARTRATE-AMINE COMPLEXES ; STACKING INTERACTIONS ; BIOLOGICAL-ACTIVITY ; CRYSTAL ; ARCHITECTURES ; NETWORKS ; DESIGN |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000230695200019 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377499 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Z |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Z,Chen, Y,Liu, P,et al. Cadmium(ii) and cobalt(ii) complexes generated from benzimidazole-5-carboxylate: self-assembly by hydrogen bonding and pi-pi interactions[J]. Journal of solid state chemistry,2005,178(7):2306-2312. |
| APA | Liu, Z,Chen, Y,Liu, P,Wang, J,&Huang, MH.(2005).Cadmium(ii) and cobalt(ii) complexes generated from benzimidazole-5-carboxylate: self-assembly by hydrogen bonding and pi-pi interactions.Journal of solid state chemistry,178(7),2306-2312. |
| MLA | Liu, Z,et al."Cadmium(ii) and cobalt(ii) complexes generated from benzimidazole-5-carboxylate: self-assembly by hydrogen bonding and pi-pi interactions".Journal of solid state chemistry 178.7(2005):2306-2312. |
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来源：中国科学院大学
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