Hydrogen-assisted unique incorporation of 1,4-divinylbenzene in copolymerization with propylene using an isospecific zirconocene catalyst
文献类型：期刊论文
| 作者 | Cao, CG; Dong, JY; Chung, TC |
| 刊名 | Macromolecular rapid communications
 |
| 出版日期 | 2005-12-22 |
| 卷号 | 26期号:24页码:1936-1941 |
| 关键词 | Copolymerization 1,4-divinylbenzene Hydrogen Metallocene catalysts Poly(propylene) |
| ISSN号 | 1022-1336 |
| DOI | 10.1002/marc.200500637 |
| 通讯作者 | Dong, jy() |
| 英文摘要 | Propylene was copolymerized with 1,4-divinylbenzene (1,4-dvb) using rac-me2si(2-me-4-ph-ind)(2)zrcl2 and mao in the presence of hydrogen. h-1 nmr spectra of the obtained copolymer confirmed the successful incorporation of 1,4-dvb. c-13 nmr analysis revealed a unique copolymer structure with the incorporated 1,4-dvb units predominantly forming 1,4-substituted phenyl repeating units in the polymer main chain. a plausible mechanism involving spontaneous insertion of terminal styryl into zr-h species was proposed to rationalize the unique incorporation of 1,4-dvb. |
| WOS关键词 | FUNCTIONALIZATION ; POLYMERIZATION ; 1,7-OCTADIENE ; PROPENE |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000234468200009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377593 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Dong, JY |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, CAS Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA |
| 推荐引用方式 GB/T 7714 | Cao, CG,Dong, JY,Chung, TC. Hydrogen-assisted unique incorporation of 1,4-divinylbenzene in copolymerization with propylene using an isospecific zirconocene catalyst[J]. Macromolecular rapid communications,2005,26(24):1936-1941. |
| APA | Cao, CG,Dong, JY,&Chung, TC.(2005).Hydrogen-assisted unique incorporation of 1,4-divinylbenzene in copolymerization with propylene using an isospecific zirconocene catalyst.Macromolecular rapid communications,26(24),1936-1941. |
| MLA | Cao, CG,et al."Hydrogen-assisted unique incorporation of 1,4-divinylbenzene in copolymerization with propylene using an isospecific zirconocene catalyst".Macromolecular rapid communications 26.24(2005):1936-1941. |
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来源：中国科学院大学
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