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Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and crystal structure of a new copper(ii) complex with 4-cyanobenzoic acid

文献类型:期刊论文

作者Li, Y; Wu, AQ; Zheng, FK; Guo, GC; Lu, CZ; Huang, JS
刊名Chinese journal of structural chemistry
出版日期2005
卷号24期号:11页码:1281-1285
关键词Copper(h) complex 4-cyanobenzoic acid Crystal structure Hydrogen bonds Pi-pi stacking
ISSN号0254-5861
通讯作者Zheng, fk()
英文摘要A new cu(ii) complex [cu(4-cba)(1,10-phen)(h2o)(2)](no3) (4-hcba = 4-cyanobenzoic acid) has been synthesized by solvothermal reaction in an ethanol/water mixed solution at 100 degrees c and structurally characterized by single-crystal x-ray diffraction. crystallographic data: c20h16cu-n4o7, m-r = 487.91, triclinic, space group p (1) over bar, a = 7.8420(2), b = 9.1070(2), c = 15.1140(6) angstrom, alpha = 76.889(9), beta = 81.332(11), gamma = 74.844(11)degrees, v = 1009.89(5) angstrom(3), z = 2, d-c = 1.605 g/cm(3), f(000) = 498, mu = 1.134 mm(-1), the final r = 0.0379 and wr = 0.0865 for 2977 observed reflections with i > 2 sigma(i). the cu(ii) atom is coordinated by two terminal water molecules, one chelating 1,10-phen molecule and one monodentate 4-cba ligand to form a slightly distorted square pyramid. the title complex molecules. are connected through hydrogen bonds and pi-pi stacking interactions to generate a 2d layered network. the thermogravimetric analysis of the title complex has also been discussed.
WOS关键词COORDINATION ; OXYGEN
WOS研究方向Chemistry ; Crystallography
WOS类目Chemistry, Inorganic & Nuclear ; Crystallography
语种英语
WOS记录号WOS:000233622200009
出版者CHINESE JOURNAL STRUCTURAL CHEMISTRY
URI标识http://www.irgrid.ac.cn/handle/1471x/2377610
专题中国科学院大学
通讯作者Zheng, FK
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Li, Y,Wu, AQ,Zheng, FK,et al. Synthesis and crystal structure of a new copper(ii) complex with 4-cyanobenzoic acid[J]. Chinese journal of structural chemistry,2005,24(11):1281-1285.
APA Li, Y,Wu, AQ,Zheng, FK,Guo, GC,Lu, CZ,&Huang, JS.(2005).Synthesis and crystal structure of a new copper(ii) complex with 4-cyanobenzoic acid.Chinese journal of structural chemistry,24(11),1281-1285.
MLA Li, Y,et al."Synthesis and crystal structure of a new copper(ii) complex with 4-cyanobenzoic acid".Chinese journal of structural chemistry 24.11(2005):1281-1285.

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来源:中国科学院大学

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