Synthesis and crystal structure of a new copper(ii) complex with 4-cyanobenzoic acid
文献类型：期刊论文
| 作者 | Li, Y; Wu, AQ; Zheng, FK; Guo, GC; Lu, CZ; Huang, JS |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2005 |
| 卷号 | 24期号:11页码:1281-1285 |
| 关键词 | Copper(h) complex 4-cyanobenzoic acid Crystal structure Hydrogen bonds Pi-pi stacking |
| ISSN号 | 0254-5861 |
| 通讯作者 | Zheng, fk() |
| 英文摘要 | A new cu(ii) complex [cu(4-cba)(1,10-phen)(h2o)(2)](no3) (4-hcba = 4-cyanobenzoic acid) has been synthesized by solvothermal reaction in an ethanol/water mixed solution at 100 degrees c and structurally characterized by single-crystal x-ray diffraction. crystallographic data: c20h16cu-n4o7, m-r = 487.91, triclinic, space group p (1) over bar, a = 7.8420(2), b = 9.1070(2), c = 15.1140(6) angstrom, alpha = 76.889(9), beta = 81.332(11), gamma = 74.844(11)degrees, v = 1009.89(5) angstrom(3), z = 2, d-c = 1.605 g/cm(3), f(000) = 498, mu = 1.134 mm(-1), the final r = 0.0379 and wr = 0.0865 for 2977 observed reflections with i > 2 sigma(i). the cu(ii) atom is coordinated by two terminal water molecules, one chelating 1,10-phen molecule and one monodentate 4-cba ligand to form a slightly distorted square pyramid. the title complex molecules. are connected through hydrogen bonds and pi-pi stacking interactions to generate a 2d layered network. the thermogravimetric analysis of the title complex has also been discussed. |
| WOS关键词 | COORDINATION ; OXYGEN |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000233622200009 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377610 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zheng, FK |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Y,Wu, AQ,Zheng, FK,et al. Synthesis and crystal structure of a new copper(ii) complex with 4-cyanobenzoic acid[J]. Chinese journal of structural chemistry,2005,24(11):1281-1285. |
| APA | Li, Y,Wu, AQ,Zheng, FK,Guo, GC,Lu, CZ,&Huang, JS.(2005).Synthesis and crystal structure of a new copper(ii) complex with 4-cyanobenzoic acid.Chinese journal of structural chemistry,24(11),1281-1285. |
| MLA | Li, Y,et al."Synthesis and crystal structure of a new copper(ii) complex with 4-cyanobenzoic acid".Chinese journal of structural chemistry 24.11(2005):1281-1285. |
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来源：中国科学院大学
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