Cp2ticl2 used as a catalyst for the transesterification between dimethyl carbonate and phenol to diphenyl carbonate
文献类型：期刊论文
| 作者 | Niu, HY; Yao, J; Wang, Y; Wang, GY |
| 刊名 | Journal of molecular catalysis a-chemical
 |
| 出版日期 | 2005-07-01 |
| 卷号 | 235期号:1-2页码:240-243 |
| 关键词 | Titanocene dichloride Transesterification Diphenyl carbonate Dimethyl carbonate Titanium ester |
| ISSN号 | 1381-1169 |
| 通讯作者 | Wang, gy() |
| 英文摘要 | Titanocene dichloride (cp2ticl2) was found to be a novel and efficient catalyst for the transesterification between dimethyl carbonate (dmc) and phenol to diphenyl carbonate (dpc). compared with other titanium esters, cp2ticl2 is more stable in air and can reach maximum catalytic activity at low catalyst amount. when the reaction was carried out between 150 and 180 degrees c, with a molar ratio of phenol to dmc of 1:1, a reaction time 10 h, a catalyst amount 0.5% (molar ratio to phenol), the conversion of phenol was 46.8%, and the selectivity of dpc and mpc was 54.9 and 43.4%, respectively. (c) 2005 elsevier b.v. all rights reserved. |
| WOS关键词 | CHEMISTRY |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000230297800030 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377621 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, GY |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Niu, HY,Yao, J,Wang, Y,et al. Cp2ticl2 used as a catalyst for the transesterification between dimethyl carbonate and phenol to diphenyl carbonate[J]. Journal of molecular catalysis a-chemical,2005,235(1-2):240-243. |
| APA | Niu, HY,Yao, J,Wang, Y,&Wang, GY.(2005).Cp2ticl2 used as a catalyst for the transesterification between dimethyl carbonate and phenol to diphenyl carbonate.Journal of molecular catalysis a-chemical,235(1-2),240-243. |
| MLA | Niu, HY,et al."Cp2ticl2 used as a catalyst for the transesterification between dimethyl carbonate and phenol to diphenyl carbonate".Journal of molecular catalysis a-chemical 235.1-2(2005):240-243. |
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来源：中国科学院大学
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