Fabrication of novel conjugated polymer nanostructure: porphyrins and fullerenes conjugately linked to the polyacetylene backbone as pendant groups
文献类型：期刊论文
| 作者 | Wang, N; Li, YJ; Lu, FS; Liu, Y; He, X; Jiang, L; Zhuang, JP; Li, XF; Li, YL; Wang, S |
| 刊名 | Journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2005-07-01 |
| 卷号 | 43期号:13页码:2851-2861 |
| 关键词 | Fullerenes High performance polymers Morphology Polyacetylenes Porphyrins |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.20757 |
| 通讯作者 | Li, yj() |
| 英文摘要 | A new series of conjugated polyacetylenes with conjugately linked fullerene and porphyrin groups as pendant units were prepared by a copolymerization reaction catalyzed by chloronorbornadiene rhodium(i)dimer-triethylamine ([rh(nbd)cl](2-)net3) in anhydrous chcl3. these polymers were characterized with uv-vis spectroscopy, fluorescence spectroscopy, and voltammetry.. scanning electron microscopy indicated that the morphology of the copolymers consisted of uniform nanorods with a diameter of about 100 nm and a length of about 300 nm. thin films of the copolymers produced steady and prompt photocurrent at an irradiation of 20.0 mw cm(-2) of white light, which was higher than that of a mixture of poly[5-(4-ethynyl-phenyl)10,15,20-tris(4-carbomethoxyphenyl)porphyrin zinc] and c-60. (c) 2005 wiley periodicals,inc. |
| WOS关键词 | PHOTOINDUCED ELECTRON-TRANSFER ; CHARGE SEPARATION ; INVERTED-REGION ; STATE ; DERIVATIVES ; DYNAMICS ; ENERGY ; DYADS ; C-60 ; RECOMBINATION |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000230014500015 |
| 出版者 | JOHN WILEY & SONS INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377782 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, YJ |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Harbin Inst Technol, Dept Appl Phys, Heilongjiang 150001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, N,Li, YJ,Lu, FS,et al. Fabrication of novel conjugated polymer nanostructure: porphyrins and fullerenes conjugately linked to the polyacetylene backbone as pendant groups[J]. Journal of polymer science part a-polymer chemistry,2005,43(13):2851-2861. |
| APA | Wang, N.,Li, YJ.,Lu, FS.,Liu, Y.,He, X.,...&Zhu, DB.(2005).Fabrication of novel conjugated polymer nanostructure: porphyrins and fullerenes conjugately linked to the polyacetylene backbone as pendant groups.Journal of polymer science part a-polymer chemistry,43(13),2851-2861. |
| MLA | Wang, N,et al."Fabrication of novel conjugated polymer nanostructure: porphyrins and fullerenes conjugately linked to the polyacetylene backbone as pendant groups".Journal of polymer science part a-polymer chemistry 43.13(2005):2851-2861. |
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来源：中国科学院大学
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