Comparison on the catalytic cracking and alkylation activities between msu-s-mfi and mcm-41 aluminosilicates
文献类型：期刊论文
| 作者 | Zheng, JL; Zhai, SR; Yang, DJ; Zhang, Y; Wu, D; Sun, YH |
| 刊名 | Acta physico-chimica sinica
 |
| 出版日期 | 2005-03-01 |
| 卷号 | 21期号:3页码:324-327 |
| 关键词 | Mesoporous aluminosilicates Catalytic cracking Alkylation Acidity |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/pku.whxb20050320 |
| 通讯作者 | Sun, yh(yhsun@sxicc.ac.cn) |
| 英文摘要 | Mesoporous aluminosilicates msu-s-mfi with well-ordered hexagonal symmetry were assembled from mfi zeolitic precursors containing abundant protozeolitic nanoclusters. normal mcm-41 was synthesized by using tetraethyl orthosilicate (teos) and sodium aluminate as silica source and aluminum source, respectively. the pore diameter of msu-s-mfi sample and normal mcm-41 both are 2.70 nm, and their bet specific surface areas and pore volumes are comparable as seen from xrd and n-2 sorption results. although both msu-s-mfi and mcm-41 possess weak acidic sites and medium strong acidic sites in nh3-tpd profiles, the density of weak acidic sites and medium strong acidic sites in msu-smm are much higher than that of mcm-41. the catalytic cracking conversion of cumene on msu-s-mfi is 31% higher than that on mcm-41 with the same si/al ratio, and the butylation conversion of naphthalene over msu-smm is 15% higher than that on the mcm-41 sample. incorporation of mfi zeolitic nanoclusters into the mesostructured framework of msu-s-mfi led to enhanced acidity. |
| WOS关键词 | MESOPOROUS MOLECULAR-SIEVES ; ALUMINUM-CHLORIDE ; NAPHTHALENE ; ISOPROPYLATION ; ZEOLITES ; SITES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000227894800020 |
| 出版者 | PEKING UNIV PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377783 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Sun, YH |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, JL,Zhai, SR,Yang, DJ,et al. Comparison on the catalytic cracking and alkylation activities between msu-s-mfi and mcm-41 aluminosilicates[J]. Acta physico-chimica sinica,2005,21(3):324-327. |
| APA | Zheng, JL,Zhai, SR,Yang, DJ,Zhang, Y,Wu, D,&Sun, YH.(2005).Comparison on the catalytic cracking and alkylation activities between msu-s-mfi and mcm-41 aluminosilicates.Acta physico-chimica sinica,21(3),324-327. |
| MLA | Zheng, JL,et al."Comparison on the catalytic cracking and alkylation activities between msu-s-mfi and mcm-41 aluminosilicates".Acta physico-chimica sinica 21.3(2005):324-327. |
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来源：中国科学院大学
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