Porous structures constructed from[simo12o40] and [siw12o40] keggin units
文献类型：期刊论文
| 作者 | Gao, SY; Cao, R; Bi, WH; Li, X; Lin, ZZ |
| 刊名 | Microporous and mesoporous materials
 |
| 出版日期 | 2005-05-02 |
| 卷号 | 80期号:1-3页码:139-145 |
| 关键词 | Keggin Polyoxometalate (pom) Crystal structure Channel |
| ISSN号 | 1387-1811 |
| DOI | 10.1016/j.micromeso.2004.11.024 |
| 通讯作者 | Cao, r() |
| 英文摘要 | Three compounds, k-2(h2o)(4)h2simo12o40 - 7h(2)o (1), k2na2(h2o)(4)siw12o40 - 4h(2)o (2), and na-4(h2o)(8)simo12o40 - 6h(2)o (3) have been synthesized and structurally characterized by single-crystal x-ray analysis, ir, and thermogravimetry. compounds 1 and 2 both show the high symmetry trigonal space group p3(2)21 and a novel 3d network structure. the keggin anions [sim12o40](4-)(m = mo, w) are linked by potassium or sodium cations to generate hexagon-shaped channels along the c-axis, in which water molecules are accommodated. compound 3 is tetragonal, space group p4/mnc constructed from [simo12o40](4-) anions and na ions. (c) 2004 elsevier inc. all rights reserved. |
| WOS关键词 | RAY CRYSTAL-STRUCTURE ; CHARGE-TRANSFER SALT ; BUILDING-BLOCKS ; PHYSICAL-PROPERTIES ; OXIDE CLUSTERS ; POLYOXOMETALATE ; COMPLEX ; POLYANIONS ; CHEMISTRY ; SOLV=H2O |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000228699400014 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2377871 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao, R |
| 作者单位 | Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Grad Sch, Fujian 350002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, SY,Cao, R,Bi, WH,et al. Porous structures constructed from[simo12o40] and [siw12o40] keggin units[J]. Microporous and mesoporous materials,2005,80(1-3):139-145. |
| APA | Gao, SY,Cao, R,Bi, WH,Li, X,&Lin, ZZ.(2005).Porous structures constructed from[simo12o40] and [siw12o40] keggin units.Microporous and mesoporous materials,80(1-3),139-145. |
| MLA | Gao, SY,et al."Porous structures constructed from[simo12o40] and [siw12o40] keggin units".Microporous and mesoporous materials 80.1-3(2005):139-145. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。