Catalytie preparation of methyl formate from methanol over silver
文献类型：期刊论文
| 作者 | Yang, Z; Li, J; Yang, XG; Wu, Y |
| 刊名 | Chemical research in chinese universities
 |
| 出版日期 | 2005-09-01 |
| 卷号 | 21期号:5页码:573-576 |
| 关键词 | Silver Methanol Methyl formate Oxygen species Synergistic effect |
| ISSN号 | 1005-9040 |
| 通讯作者 | Yang, xg() |
| 英文摘要 | A catalytic reaction over a silver catalyst performed in an unregarded temperature region(473-873 k), with a long catalytic lifetime for the production of methyl formate from methanol was provided. as a potential preparing route. the optimal yield of methyl formate(ca. 14.8%) with a selectivity > 90% was obtained at about 573 k. because alpha-oxygen species and bulk oxygen species coexist in the unregarded temperature region, a synergistic process concerning alpha-oxygen species and bulk oxygen species was proved over o-alpha-rich and o-gamma-rich samples. |
| WOS关键词 | ELECTROLYTIC SILVER ; PARTIAL OXIDATION ; DEHYDROGENATION ; OXYGEN ; CARBONYLATION ; FORMALDEHYDE ; ETHYLENE ; MODEL ; RAMAN ; TPD |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000232473700017 |
| 出版者 | HIGHER EDUCATION PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378045 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yang, XG |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Z,Li, J,Yang, XG,et al. Catalytie preparation of methyl formate from methanol over silver[J]. Chemical research in chinese universities,2005,21(5):573-576. |
| APA | Yang, Z,Li, J,Yang, XG,&Wu, Y.(2005).Catalytie preparation of methyl formate from methanol over silver.Chemical research in chinese universities,21(5),573-576. |
| MLA | Yang, Z,et al."Catalytie preparation of methyl formate from methanol over silver".Chemical research in chinese universities 21.5(2005):573-576. |
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来源：中国科学院大学
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