A novel 3d cyanide-bridging mixed-valence copper (i/ii) coordination polymer: [cu-ii(cn)(2)(dmf)(4)cu-4(i)(cn)(4)]
文献类型:期刊论文
作者 | Liu, B; Xu, L; Guo, GC; Huang, JS |
刊名 | Inorganic chemistry communications
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出版日期 | 2005-09-01 |
卷号 | 8期号:9页码:796-799 |
关键词 | Cyanide-bridging Mixed-valence copper Solid-state emission spectrum Diffuse reflectance uv-vis spectra |
ISSN号 | 1387-7003 |
DOI | 10.1016/j.inoche.2005.05.024 |
通讯作者 | Guo, gc() |
英文摘要 | [cu-ii(cn)(2)(dmf)(4) cu-4(1)(cn)(4)], [crystal data: monoclinic, c-2/c, a = 14.0687(12), b = 12.6223(10), c = 16.4367(12) angstrom, beta = 92.001(6)degrees, v = 2917.0(4) angstrom(3), z = 4], a novel cyanide-bridging mixed-valence cu-ii/cu-i coordination polymer was hydrothermally synthesized, and crystallographically characterized to be a 3d coordination network constructed from the interpenetrating double-layers containing the largest 36-membered m-cn-m rings and the strong cu... cu interactions. the present compound was characterized using ir and elemental analysis, fluorescence spectrum and diffuse reflectance uv-vis spectrum. (c) 2005 elsevier b.v. all rights reserved. |
WOS关键词 | DOUBLE SALTS ; CRYSTAL-STRUCTURES ; DONOR LIGANDS ; COMPLEXES ; CU ; STATE ; LUMINESCENT ; CHEMISTRY ; ISOMERISM ; CENTERS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear |
语种 | 英语 |
WOS记录号 | WOS:000231581300011 |
出版者 | ELSEVIER SCIENCE BV |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378051 |
专题 | 中国科学院大学 |
通讯作者 | Guo, GC |
作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, B,Xu, L,Guo, GC,et al. A novel 3d cyanide-bridging mixed-valence copper (i/ii) coordination polymer: [cu-ii(cn)(2)(dmf)(4)cu-4(i)(cn)(4)][J]. Inorganic chemistry communications,2005,8(9):796-799. |
APA | Liu, B,Xu, L,Guo, GC,&Huang, JS.(2005).A novel 3d cyanide-bridging mixed-valence copper (i/ii) coordination polymer: [cu-ii(cn)(2)(dmf)(4)cu-4(i)(cn)(4)].Inorganic chemistry communications,8(9),796-799. |
MLA | Liu, B,et al."A novel 3d cyanide-bridging mixed-valence copper (i/ii) coordination polymer: [cu-ii(cn)(2)(dmf)(4)cu-4(i)(cn)(4)]".Inorganic chemistry communications 8.9(2005):796-799. |
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来源:中国科学院大学
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