Hydrothermal syntheses, crystal structures and characterizations of three new copper coordination polymers
文献类型：期刊论文
| 作者 | Wen, YH; Cheng, HK; Feng, YL; Zhang, H; Li, ZH; Yao, YG |
| 刊名 | Inorganica chimica acta
 |
| 出版日期 | 2005-08-01 |
| 卷号 | 358期号:12页码:3347-3354 |
| ISSN号 | 0020-1693 |
| 关键词 | Hydrothermat synthesis Reaction condition Coordination architecture Mixed ligand Copper complex |
| DOI | 10.1016/j.ica.2005.05.004 |
| 通讯作者 | Yao, yg() |
| 英文摘要 | Three new copper complexes, [(cucui)-cu-ii(ip)(iph)(4,4'-bipy)(3/2)](n) (1), [cu(ip)(4,4'-bipy)](n)center dot 3nh(2)o (2), and [cu(iph)(2)(4,4'-bipy)](n), (3), have been hydrothermally synthesized by the reaction of cu(no3)(2) center dot 3h(2)o with isophthalic acid (iph(2)) and 4,4'-bipyridine (4,4'-bipy) under different reaction conditions. complex 1, a mixed-valence copper(1,11) complex, exhibits a 2-d) interpenetrating grid framework, in which five-coordinated cull and three-coordinated cu-i environments are established. the oxidation states of center cu atoms have been confirmed by x-ray photoelectron spectroscopy (xps) and electron paramagnetic resonance spectra (epr). complex 2 features a 2-d box-like bilayer architecture, in which cull atoms are linked by ip ligands to form a 1-d double-chain and the resulting chains are further strutted by the 4,4'-bipy ligands. in complex 3, two bridging 4,4'-bipy ligands and two terminal iph ligands confine the cull center in a square plane coordination geometry. the whole molecule of 3 was arranged into a 1-d linear chain structure. additionally, the thermogravimetric analyses (tga) for complexes 1-3 are also discussed in this paper. (c) 2005 elsevier b.v. all rights reserved. |
| WOS关键词 | SECONDARY BUILDING UNITS ; METAL-ORGANIC FRAMEWORK ; MAGNETIC-PROPERTIES ; NETWORK ; TEMPERATURE ; COMPLEXES ; MOLECULES ; CHANNELS ; CHAINS ; REDOX |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE SA |
| WOS记录号 | WOS:000231437700009 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378059 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yao, YG |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Zhejiang Normal Univ, Inst Chem Phys, Jinhua 321004, Zhejiang, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen, YH,Cheng, HK,Feng, YL,et al. Hydrothermal syntheses, crystal structures and characterizations of three new copper coordination polymers[J]. Inorganica chimica acta,2005,358(12):3347-3354. |
| APA | Wen, YH,Cheng, HK,Feng, YL,Zhang, H,Li, ZH,&Yao, YG.(2005).Hydrothermal syntheses, crystal structures and characterizations of three new copper coordination polymers.Inorganica chimica acta,358(12),3347-3354. |
| MLA | Wen, YH,et al."Hydrothermal syntheses, crystal structures and characterizations of three new copper coordination polymers".Inorganica chimica acta 358.12(2005):3347-3354. |
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来源：中国科学院大学
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