Development of chiral catalysts by asymmetric activation for highly enantioselective diethylzinc addition to imines
文献类型：期刊论文
| 作者 | Zhang, HL; Liu, H; Cui, X; Mi, AQ; Jiang, YZ; Gong, LZ |
| 刊名 | Synlett
 |
| 出版日期 | 2005-03-04 |
| 期号 | 4页码:615-618 |
| 关键词 | Asymmetric dialkylzinc addition Asymmetric activation Imine |
| ISSN号 | 0936-5214 |
| DOI | 10.1055/s-2005-863709 |
| 通讯作者 | Gong, lz() |
| 英文摘要 | Based on the asymmetric activation concept, a library of chiral zinc complexes in situ formed by the combination of diimines derived from chiral 1,2-diphenyl-ethanene-1,2-diamine, binol derivatives, and diethylzinc are evaluated in the asymmetric addition of diethylzinc to n-acylimines. in the presence of 10 mol% l3zna1, high enantioselectivities and yields were provided for a wide range of aromatic imines in 1,2-dichloroethane at -25 degrees c. |
| WOS关键词 | ENANTIOMER-SELECTIVE ACTIVATION ; N-(DIPHENYLPHOSPHINOYL) IMINES ; N-DIPHENYLPHOSPHINOYLIMINES ; ORGANOMETALLIC REAGENTS ; DIALKYLZINC REAGENTS ; NITROGEN ACTIVATORS ; AZIRIDINO ALCOHOLS ; RACEMIC CATALYSTS ; LIGANDS ; AMINES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000227583700013 |
| 出版者 | GEORG THIEME VERLAG KG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378062 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Gong, LZ |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Asymmetr Synt & Chirotechnol Sichuan Prov, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Union Lab Asymmetr Synth, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, HL,Liu, H,Cui, X,et al. Development of chiral catalysts by asymmetric activation for highly enantioselective diethylzinc addition to imines[J]. Synlett,2005(4):615-618. |
| APA | Zhang, HL,Liu, H,Cui, X,Mi, AQ,Jiang, YZ,&Gong, LZ.(2005).Development of chiral catalysts by asymmetric activation for highly enantioselective diethylzinc addition to imines.Synlett(4),615-618. |
| MLA | Zhang, HL,et al."Development of chiral catalysts by asymmetric activation for highly enantioselective diethylzinc addition to imines".Synlett .4(2005):615-618. |
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来源：中国科学院大学
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