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Functions of fluorosurfactants 1: surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant

文献类型:期刊论文

作者Song, AX; Dong, SL; Hao, JC; Liu, WM; Xu, GY; Wang, HQ
刊名Journal of fluorine chemistry
出版日期2005-10-01
卷号126期号:9-10页码:1266-1273
关键词Fluorosurfactants Surface-activity Phase behavior Vesicles Ff-tem
ISSN号0022-1139
DOI10.1016/j.jfluchem.2005.06.005
通讯作者Hao, jc()
英文摘要Surface-activity of a short-tailed chain hydrocarbon surfactant, heptane-1-sulfonic acid sodium salt (c7sna), was studied by using surface tension and conductivity measurements, which the surface-activity was improved largely by the addition of small amount of a fluorosurfactant, 1h,1h,2h,2h,3h,3h,4h,4h-heneicosafluorotetradecylpyridinium iodine (hftpi). the phase behavior and vesicle formation of c-h/c-f surfactant mixtures in aqueous solutions are similar to ones of cationic-anionic surfactant (catanionic) systems. the birefringent, viscoelastic l alpha-phase consisting of unilamellar and multilamellar vesicles can be observed, which were determined by freeze-fracture transmission electron microscopy (ff-tem) images. the theological properties of l alpha-phase samples were measured. h-1 and f-19 nmr spectra were measured to monitor the information of self-assemblies of c7sna and hftpi in l-1-phase (spherical micelles) and l alpha-phase (vesicles). the results show that the c-h micelles and c-f micelles form in aqueous solutions individually. in l alpha-phase (vesicles), the interaction between anionic hydrocarbon (c7sna) and cationic fluorocarbon (hftpi) surfactants exist due to the strong electric static interaction of opposite charge head groups. (c) 2005 elsevier b.v. all rights reserved.
WOS关键词ANIONIC SURFACTANT ; MICELLAR SOLUTIONS ; WATER-SYSTEM ; MIXTURES ; LENGTH ; PHASE ; OXIDE
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear ; Chemistry, Organic
语种英语
WOS记录号WOS:000232818200001
出版者ELSEVIER SCIENCE SA
URI标识http://www.irgrid.ac.cn/handle/1471x/2378144
专题中国科学院大学
通讯作者Hao, JC
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Song, AX,Dong, SL,Hao, JC,et al. Functions of fluorosurfactants 1: surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant[J]. Journal of fluorine chemistry,2005,126(9-10):1266-1273.
APA Song, AX,Dong, SL,Hao, JC,Liu, WM,Xu, GY,&Wang, HQ.(2005).Functions of fluorosurfactants 1: surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant.Journal of fluorine chemistry,126(9-10),1266-1273.
MLA Song, AX,et al."Functions of fluorosurfactants 1: surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant".Journal of fluorine chemistry 126.9-10(2005):1266-1273.

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来源:中国科学院大学

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