Asymmetric direct vinylogous michael reaction of activated alkenes to nitroolefins catalyzed by modified cinchona alkaloids
文献类型：期刊论文
| 作者 | Xue, D; Chen, YC; Wang, QW; Cun, LF; Zhu, J; Deng, JG |
| 刊名 | Organic letters
 |
| 出版日期 | 2005-11-10 |
| 卷号 | 7期号:23页码:5293-5296 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/ol052283b |
| 通讯作者 | Chen, yc(jgdeng@cioc.oc.cn) |
| 英文摘要 | The first organocatalytic and asymmetric direct vinylogous michael reaction that employs the electron-deficient vinyl malononitriles as the nucleophilic species has been reported. the novel transformations exhibit exclusive gamma-selectivity and high diastereo- and enantioselectivity in the addition to nitroolefins, which give the multifunctional products with two vicinal chiral centers. |
| WOS关键词 | ENANTIOSELECTIVE CONJUGATE ADDITION ; SUBSTITUTED ALPHA-CYANOACETATES ; RUTHENIUM AMIDO COMPLEXES ; TRANSFER HYDROGENATION ; MANNICH REACTIONS ; QUATERNARY ; STEREOCENTERS ; AMINATION ; MALONATE ; OLEFINS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000233259000046 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378180 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, YC |
| 作者单位 | 1.Sichuan Univ, W China Sch Pharm, Dept Med Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China 3.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol, Sichuan Prov & Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, D,Chen, YC,Wang, QW,et al. Asymmetric direct vinylogous michael reaction of activated alkenes to nitroolefins catalyzed by modified cinchona alkaloids[J]. Organic letters,2005,7(23):5293-5296. |
| APA | Xue, D,Chen, YC,Wang, QW,Cun, LF,Zhu, J,&Deng, JG.(2005).Asymmetric direct vinylogous michael reaction of activated alkenes to nitroolefins catalyzed by modified cinchona alkaloids.Organic letters,7(23),5293-5296. |
| MLA | Xue, D,et al."Asymmetric direct vinylogous michael reaction of activated alkenes to nitroolefins catalyzed by modified cinchona alkaloids".Organic letters 7.23(2005):5293-5296. |
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来源：中国科学院大学
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