Control and development of crystallinity and morphology in poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate)/poly(propylene carbonate) blends
文献类型:期刊论文
作者 | Li, J; Lai, MF; Liu, JJ |
刊名 | Journal of applied polymer science
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出版日期 | 2005-11-05 |
卷号 | 98期号:3页码:1427-1436 |
关键词 | Biodegradable Blends Crystallization Morphology Reactive processing |
ISSN号 | 0021-8995 |
DOI | 10.1002/app.22117 |
通讯作者 | Liu, jj() |
英文摘要 | Two different methodologies (reactive blending and mechanical blending) for preparing blends of poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate) (phbv) and poly(propylene carbonate) (ppc) were used. the miscibility, chemical structure, thermal behavior, crystallinity, morphology, and mechanical properties of the blends were investigated with fourier transform infrared spectroscopy, differential scanning calorimetry, polarized optical microscopy, scanning electron microscopy, and tensile tests. a certain extent of hydrogen-bonding interactions between phbv and ppc took place in the blends. the graft copolymerization was confirmed in the reactive system. the incorporation of ppc hampered the crystallization process of phbv and evidently altered the morphology, and the effect was enhanced in the reactive blend. the mechanical properties of phbv could be changed by 1-2 orders of magnitude by blending modification. (c) 2005 wiley periodicals, inc. |
WOS关键词 | MECHANICAL-PROPERTIES ; BACTERIAL POLY<(R)-3-HYDROXYBUTYRATE> ; CRYSTALLIZATION PHENOMENA ; POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYVALERATE) ; MISCIBILITY ; COPOLYMERIZATION ; DIOXIDE ; POLY(HYDROXYBUTYRATE) ; BIODEGRADATION ; POLYALCOHOLS |
WOS研究方向 | Polymer Science |
WOS类目 | Polymer Science |
语种 | 英语 |
WOS记录号 | WOS:000231830500066 |
出版者 | JOHN WILEY & SONS INC |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378191 |
专题 | 中国科学院大学 |
通讯作者 | Liu, JJ |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Li, J,Lai, MF,Liu, JJ. Control and development of crystallinity and morphology in poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate)/poly(propylene carbonate) blends[J]. Journal of applied polymer science,2005,98(3):1427-1436. |
APA | Li, J,Lai, MF,&Liu, JJ.(2005).Control and development of crystallinity and morphology in poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate)/poly(propylene carbonate) blends.Journal of applied polymer science,98(3),1427-1436. |
MLA | Li, J,et al."Control and development of crystallinity and morphology in poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate)/poly(propylene carbonate) blends".Journal of applied polymer science 98.3(2005):1427-1436. |
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来源:中国科学院大学
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