Synthesis and crystal structure of a heterotrinuclear compound [pdcu2(tdt)(mu-dppm)(2)(mecn)(4)]-(clo4)(2)center dot 2/3h(2)o(tdt=3,4-toluenedithiolate, dppm = bis(diphenylphosphino)methane
文献类型：期刊论文
| 作者 | Qin, YH; Wu, MM; Chen, ZN |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2005 |
| 卷号 | 24期号:6页码:621-624 |
| ISSN号 | 0254-5861 |
| 关键词 | Copper Crystal structure Dppm Palladium 3,4-toluenedithiolate |
| 通讯作者 | Chen, zn() |
| 英文摘要 | The heterotrinuclear compound [pdcu2(tdt)(mu-dppm)(2)(mecn)(4)](clo4)(2)center dot 2/3h(2)o 1 (tdt = 3,4-toluenedithiolate, dppm = bis(diphenylphosphino)methane) has been prepared and characterized by x-ray structural analysis. compound i crystallizes in trigonal system, space group r3c with a = b = 34.4275(3), c = 32.6700(5) angstrom, v = 33534.4(7) angstrom(3), m-r = 1527.2 1, z = 18, d-c = 1.361 g/cm(3), f(000) 13974, mu(mok alpha) = 1.069 mm(-1), the final r = 0.0703 and wr = 0.1389 for 8375 observed reflections with i > 2 sigma(i). the dithiolate tdt displays a chelating and bridging coordination mode, which chelates a pd-ii and bridges two cu-i atoms. the pd-ii center is located in an approximate square-planar environment with s2p2 donors, and each cu-i center exhibits a tetrahedral geometry. |
| WOS关键词 | METAL DIPHOSPHINE ; COMPLEXES ; COMPONENTS ; LIGANDS ; PHOSPHINE ; THIOLATE |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| WOS记录号 | WOS:000230101800001 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378272 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, ZN |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, YH,Wu, MM,Chen, ZN. Synthesis and crystal structure of a heterotrinuclear compound [pdcu2(tdt)(mu-dppm)(2)(mecn)(4)]-(clo4)(2)center dot 2/3h(2)o(tdt=3,4-toluenedithiolate, dppm = bis(diphenylphosphino)methane[J]. Chinese journal of structural chemistry,2005,24(6):621-624. |
| APA | Qin, YH,Wu, MM,&Chen, ZN.(2005).Synthesis and crystal structure of a heterotrinuclear compound [pdcu2(tdt)(mu-dppm)(2)(mecn)(4)]-(clo4)(2)center dot 2/3h(2)o(tdt=3,4-toluenedithiolate, dppm = bis(diphenylphosphino)methane.Chinese journal of structural chemistry,24(6),621-624. |
| MLA | Qin, YH,et al."Synthesis and crystal structure of a heterotrinuclear compound [pdcu2(tdt)(mu-dppm)(2)(mecn)(4)]-(clo4)(2)center dot 2/3h(2)o(tdt=3,4-toluenedithiolate, dppm = bis(diphenylphosphino)methane".Chinese journal of structural chemistry 24.6(2005):621-624. |
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来源：中国科学院大学
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