Formation of o-phenylenediamine oligomers and their self-assembly into one-dimensional structures in aqueous medium
文献类型:期刊论文
作者 | Sun, XP; Dong, SJ; Wang, EK |
刊名 | Macromolecular rapid communications
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出版日期 | 2005-09-23 |
卷号 | 26期号:18页码:1504-1508 |
关键词 | Gel permeation chromatography (gpc) Hydrogen bonding One-dimensional structure O-phenylenediamine Pi-pi interaction Self-assembly |
ISSN号 | 1022-1336 |
DOI | 10.1002/marc.200500502 |
通讯作者 | Dong, sj(ekwang@ciac.jl.cn) |
英文摘要 | Uniform one-dimensional (1d) structures of o-phenylenediamine (opd) oligomers are obtained by direct mix of agno3 and opd aqueous solutions at room temperature. the formation of the 1d structures involves two stages: (1) oxidation of opd by agno3, yielding individual opd oligomers; and (2) self-assembly of the oligomers, forming the 1d structures. upon decreasing medium ph, the 1d structures can break-apart to form individual oligomers, or vice versa. it is also found that both the concentration and molar ratio of reactants can influence the morphology of the structures thus formed. |
WOS关键词 | ELECTRONICALLY CONDUCTIVE POLYMERS ; GLASSY-CARBON ELECTRODES ; TEMPLATE SYNTHESIS ; HYDROGEN-PEROXIDE ; POLY(O-PHENYLENEDIAMINE) FILM ; POLYANILINE ; NANOSTRUCTURES ; REDUCTION ; POLY(ORTHO-PHENYLENEDIAMINE) ; POLYMERIZATION |
WOS研究方向 | Polymer Science |
WOS类目 | Polymer Science |
语种 | 英语 |
WOS记录号 | WOS:000232327600012 |
出版者 | WILEY-V C H VERLAG GMBH |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378278 |
专题 | 中国科学院大学 |
通讯作者 | Dong, SJ |
作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, XP,Dong, SJ,Wang, EK. Formation of o-phenylenediamine oligomers and their self-assembly into one-dimensional structures in aqueous medium[J]. Macromolecular rapid communications,2005,26(18):1504-1508. |
APA | Sun, XP,Dong, SJ,&Wang, EK.(2005).Formation of o-phenylenediamine oligomers and their self-assembly into one-dimensional structures in aqueous medium.Macromolecular rapid communications,26(18),1504-1508. |
MLA | Sun, XP,et al."Formation of o-phenylenediamine oligomers and their self-assembly into one-dimensional structures in aqueous medium".Macromolecular rapid communications 26.18(2005):1504-1508. |
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来源:中国科学院大学
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