Asymmetric transfer hydrogenation of ketones catalyzed by hydrophobic metal-amido complexes in aqueous micelles and vesicles
文献类型：期刊论文
| 作者 | Wang, F; Liu, H; Cun, LF; Zhu, J; Deng, JG; Jiang, YZ |
| 刊名 | Journal of organic chemistry
 |
| 出版日期 | 2005-11-11 |
| 卷号 | 70期号:23页码:9424-9429 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/jo0514826 |
| 通讯作者 | Deng, jg() |
| 英文摘要 | Asymmetric transfer hydrogenation of ketones, especially (x-bromomethyl aromatic ketones, catalyzed by unmodified, hydrophobic transition metal-amido complexes (tsdpen-m), was performed successfully with significant enhancement of activity, chemoselectivity, and enantioselectivity (up to 99% ee) in aqueous media containing micelles and vesicles. the hydrophobic catalyst, embedded in micelles constructed from the surfactant cetyltrimethylammonium bromide (ctab), could be separated from the organic phase along with the products and was recycled for at least six times. |
| WOS关键词 | SOLUBLE AMINOSULFONAMIDE LIGANDS ; DIELS-ALDER REACTION ; AROMATIC KETONES ; CARBONYL-COMPOUNDS ; CHIRAL RHODIUM ; ENANTIOSELECTIVE REDUCTION ; PRACTICAL SYNTHESIS ; ORGANIC-REACTIONS ; LEWIS-ACID ; WATER |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000233209400040 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378342 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Deng, JG |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, F,Liu, H,Cun, LF,et al. Asymmetric transfer hydrogenation of ketones catalyzed by hydrophobic metal-amido complexes in aqueous micelles and vesicles[J]. Journal of organic chemistry,2005,70(23):9424-9429. |
| APA | Wang, F,Liu, H,Cun, LF,Zhu, J,Deng, JG,&Jiang, YZ.(2005).Asymmetric transfer hydrogenation of ketones catalyzed by hydrophobic metal-amido complexes in aqueous micelles and vesicles.Journal of organic chemistry,70(23),9424-9429. |
| MLA | Wang, F,et al."Asymmetric transfer hydrogenation of ketones catalyzed by hydrophobic metal-amido complexes in aqueous micelles and vesicles".Journal of organic chemistry 70.23(2005):9424-9429. |
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来源：中国科学院大学
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