Preparation of chiral 7,7 '-disubstituted binaps for rh-catalyzed 1,4-addition of arylboronic acids
文献类型：期刊论文
| 作者 | Yuan, WC; Cun, LF; Gong, LZ; Mi, AQ; Jiang, YZ |
| 刊名 | Tetrahedron letters
 |
| 出版日期 | 2005-01-17 |
| 卷号 | 46期号:3页码:509-512 |
| 关键词 | 7.7 '-disubstittited binap 1,4-addition Arylboronic acids Asymmetric catalysis |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2004.11.096 |
| 通讯作者 | Gong, lz() |
| 英文摘要 | A series of new 7,7'-disubstituted binaps were readily prepared starting with an asymmetric catalytic oxidative coupling. they were applied as ligands to rhodium catalyzed 1,4-addition of arylboronic acids to enone,. resulting in enantioselectvities of up to 99% ee. the enantioselectivity was found to be dependent oil the size of achiral substituents. (c) 2004 elsevier ltd. all rights reserved. |
| WOS关键词 | ASYMMETRIC CONJUGATE ADDITION ; ALPHA,BETA-UNSATURATED ESTERS ; OXOVANADIUM(IV) COMPLEXES ; LIGANDS ; REAGENTS ; ENONES ; PHOSPHORAMIDITES ; CYCLOALKENONES ; 2-NAPHTHOLS ; ARYL |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000226332600034 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378347 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Gong, LZ |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan, Prov & Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, WC,Cun, LF,Gong, LZ,et al. Preparation of chiral 7,7 '-disubstituted binaps for rh-catalyzed 1,4-addition of arylboronic acids[J]. Tetrahedron letters,2005,46(3):509-512. |
| APA | Yuan, WC,Cun, LF,Gong, LZ,Mi, AQ,&Jiang, YZ.(2005).Preparation of chiral 7,7 '-disubstituted binaps for rh-catalyzed 1,4-addition of arylboronic acids.Tetrahedron letters,46(3),509-512. |
| MLA | Yuan, WC,et al."Preparation of chiral 7,7 '-disubstituted binaps for rh-catalyzed 1,4-addition of arylboronic acids".Tetrahedron letters 46.3(2005):509-512. |
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来源：中国科学院大学
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