A facile synthesis of homotriptycenes from anthranol derivatives
文献类型：期刊论文
| 作者 | Cao, DR; Gao, CM; Meier, H |
| 刊名 | Synlett
 |
| 出版日期 | 2005-12-19 |
| 期号 | 20页码:3166-3168 |
| 关键词 | Aromatization Condensation Electrophilic substitution Transannular ring closure |
| ISSN号 | 0936-5214 |
| DOI | 10.1055/s-2005-921929 |
| 英文摘要 | Substituted trans-10-benzyl-9-anthranols 5a,b and substituted 10,10-dibenzyl-9-anthranol 8e undergo intramolecular cyclization in the presence of formic or oxalic acid to give homotriptycenes 9a,b,e. depending on the amount of acid used, a competitive 1,4-dehydration to anthracene derivatives 10a,b was observed for 5a,b. the latter process was the only reaction pathway for anthranols that do not possess electron-donating substituents on benzyl moiety (5c,d -> 10c,d). |
| WOS关键词 | MODEL QUINONE METHIDES ; TRIPTYCENE ; ANTHRAHYDROQUINONE ; CRYSTALS ; ADDUCTS ; PACKING ; TRIADS ; DIADS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000235012400036 |
| 出版者 | GEORG THIEME VERLAG KG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378362 |
| 专题 | 中国科学院大学 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Chem, LCLC, Guangzhou 510650, Peoples R China 2.S China Univ Technol, Coll Chem, Guangzhou 510641, Peoples R China 3.CAS, Grad Sch, Beijing 100039, Peoples R China 4.Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany |
| 推荐引用方式 GB/T 7714 | Cao, DR,Gao, CM,Meier, H. A facile synthesis of homotriptycenes from anthranol derivatives[J]. Synlett,2005(20):3166-3168. |
| APA | Cao, DR,Gao, CM,&Meier, H.(2005).A facile synthesis of homotriptycenes from anthranol derivatives.Synlett(20),3166-3168. |
| MLA | Cao, DR,et al."A facile synthesis of homotriptycenes from anthranol derivatives".Synlett .20(2005):3166-3168. |
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来源：中国科学院大学
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