Copolymerization of co2 and cyclohexene oxide using a bdie center dot[zn-al] catalyst
文献类型：期刊论文
| 作者 | You, JX; Zhang, M; Liu, BH; Chen, LB; Wu, GF; Zhang, SW |
| 刊名 | Acta polymerica sinica
 |
| 出版日期 | 2005-10-01 |
| 期号 | 5页码:750-753 |
| 关键词 | Carbon dioxide Cyclohexene oxide Copolymerization Bdie center dot[zn-al] |
| ISSN号 | 1000-3304 |
| 通讯作者 | You, jx() |
| 英文摘要 | A novel catalyst for the copolymerization, of co2 and cyclohexene oxide was prepared by using zinc acetate anhydrous, aluminum isopropoxide and precursor n, n'-bis (2,6-diisopropylphenyl)-2,4-ethyldiimine (bdie). comparing with other. similar catalytic systems prepared with diethyl zinc, it is of low cost and easy to handle. the resulted copolymers were characterized by ir and nmr. effects of reaction conditions such as reaction time and temperature, co2 pressure, and catalyst concentration on copolymerization were. investigated. a highest catalytic efficiency of 31.6 g copolymer/g cat was obtained at 80 degrees c with catalyst concentration of 0.1 g/ml, bdie:[zn-al] = 1:2 and co2 pressure of 2 mpa in a 24 h period of reaction. |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000232858500021 |
| 出版者 | SCIENCE PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378391 |
| 专题 | 中国科学院大学 |
| 通讯作者 | You, JX |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | You, JX,Zhang, M,Liu, BH,et al. Copolymerization of co2 and cyclohexene oxide using a bdie center dot[zn-al] catalyst[J]. Acta polymerica sinica,2005(5):750-753. |
| APA | You, JX,Zhang, M,Liu, BH,Chen, LB,Wu, GF,&Zhang, SW.(2005).Copolymerization of co2 and cyclohexene oxide using a bdie center dot[zn-al] catalyst.Acta polymerica sinica(5),750-753. |
| MLA | You, JX,et al."Copolymerization of co2 and cyclohexene oxide using a bdie center dot[zn-al] catalyst".Acta polymerica sinica .5(2005):750-753. |
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来源：中国科学院大学
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