Study of an iron-manganese fischer-tropsch synthesis catalyst promoted with copper
文献类型:期刊论文
作者 | Zhang, CH; Yang, Y; Teng, BT; Li, TZ; Zheng, HY; Xiang, HW; Li, YW |
刊名 | Journal of catalysis |
出版日期 | 2006-01-25 |
卷号 | 237期号:2页码:405-415 |
ISSN号 | 0021-9517 |
关键词 | Fischer-tropsch synthesis Fe-mn catalyst Copper promotion Metal-support interaction |
DOI | 10.1016/j.jcat.2005.11.004 |
通讯作者 | Li, yw() |
英文摘要 | The metal-silica interaction and catalytic behavior of cu-promoted fe-mn-k/sio2 catalysts were investigated by temperature-programmed reduction/desorption (tpr/-tpd), differential thermogravimetric analysis, in situ diffuse reflectance infrared fourier transform analysis, and mossbauer spectroscopy. the fischer-tropsch synthesis (fts) performance of the catalysts with or without copper was studied in a slurry-phase continuously stirred tank reactor. the characterization results indicate that several kinds of metal oxide-silica interactions are present oil fe-mnk/sio2 catalysts with or without copper, which include iron-silica, copper-silica, and potassium-silica interactions. in addition to the well-known effect of cu promoter on casing the reduction of iron-based fts catalysts, it is found that cu promoter call increase the rate of carburization, but does not vary the extent of carburization during the steady-state fts reaction. the basicity of the cu and k co-promoted catalyst is greatly enhanced, as demonstrated by co2-tpd results. in the fts reaction, cu improves the rate of catalyst activation and shortens the induction period, whereas the addition of cu has no apparent influence on the steady-state activity of the catalyst. promotion of cu strongly affects hydrocarbon selectivity. the product distribution shifts to heavy hydrocarbons, and the olefin/paraffin ratio is enhanced on the catalyst due to the indirect enhancement of surface basicity by the copper promotion effect. (c) 2005 elsevier inc. all rights reserved. |
WOS关键词 | TEMPERATURE-PROGRAMMED REDUCTION ; DIFFUSE-REFLECTANCE FTIR ; SUPPORTED IRON ; CARBON-MONOXIDE ; OXIDE CATALYSTS ; MOSSBAUER-SPECTROSCOPY ; ADSORPTION ; SURFACE ; PHASE ; SELECTIVITY |
WOS研究方向 | Chemistry ; Engineering |
WOS类目 | Chemistry, Physical ; Engineering, Chemical |
语种 | 英语 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
WOS记录号 | WOS:000235330600020 |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378408 |
专题 | 中国科学院大学 |
通讯作者 | Li, YW |
作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, CH,Yang, Y,Teng, BT,et al. Study of an iron-manganese fischer-tropsch synthesis catalyst promoted with copper[J]. Journal of catalysis,2006,237(2):405-415. |
APA | Zhang, CH.,Yang, Y.,Teng, BT.,Li, TZ.,Zheng, HY.,...&Li, YW.(2006).Study of an iron-manganese fischer-tropsch synthesis catalyst promoted with copper.Journal of catalysis,237(2),405-415. |
MLA | Zhang, CH,et al."Study of an iron-manganese fischer-tropsch synthesis catalyst promoted with copper".Journal of catalysis 237.2(2006):405-415. |
入库方式: iSwitch采集
来源:中国科学院大学
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