Crystallization and structural evolution of yf3-sio2 xerogel
文献类型:期刊论文
作者 | Luo, WQ; Wang, YS; Cheng, Y; Bao, F; Zhou, LH |
刊名 | Materials science and engineering b-solid state materials for advanced technology
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出版日期 | 2006-02-25 |
卷号 | 127期号:2-3页码:218-223 |
关键词 | Sol-gel Glass ceramics Yf3 crystallites Microstructure Textural property |
ISSN号 | 0921-5107 |
DOI | 10.1016/j.mseb.2005.10.034 |
通讯作者 | Wang, ys() |
英文摘要 | Yf3-sio2 glass-ceramic was prepared by sol-gel method for the first time. when the xerogel was heat-treated to 400 degrees c, yf3 crystallites sized around 5 nm were precipitated from the silica matrix and aggregated together to form 50-100 nm congeries particles. with further increasing of the temperature, yf3 crystallites tended to separate from the congeries with their sizes unchanged, resulting finally in a homogeneous distribution among the glassy matrix. the crystallization activation energy of yf3 was evaluated to be 129 and 139 kj/mol by kissinger's method and chen's method through non-isothermal experiments, respectively, implying that the crystallization is controlled by long-range atomic diffusion. the evolution of textural properties of yf3-sio2 glass ceramics with temperature was also investigated mainly through n-2 adsorption experiments. (c) 2005 elsevier b.v. all rights reserved. |
WOS关键词 | UP-CONVERSION ; ADSORPTION ; CRYSTALS ; GASES ; ER3+ |
WOS研究方向 | Materials Science ; Physics |
WOS类目 | Materials Science, Multidisciplinary ; Physics, Condensed Matter |
语种 | 英语 |
WOS记录号 | WOS:000235440900023 |
出版者 | ELSEVIER SCIENCE SA |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378441 |
专题 | 中国科学院大学 |
通讯作者 | Wang, YS |
作者单位 | Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Grad Sch, Fuzhou 350002, Peoples R China |
推荐引用方式 GB/T 7714 | Luo, WQ,Wang, YS,Cheng, Y,et al. Crystallization and structural evolution of yf3-sio2 xerogel[J]. Materials science and engineering b-solid state materials for advanced technology,2006,127(2-3):218-223. |
APA | Luo, WQ,Wang, YS,Cheng, Y,Bao, F,&Zhou, LH.(2006).Crystallization and structural evolution of yf3-sio2 xerogel.Materials science and engineering b-solid state materials for advanced technology,127(2-3),218-223. |
MLA | Luo, WQ,et al."Crystallization and structural evolution of yf3-sio2 xerogel".Materials science and engineering b-solid state materials for advanced technology 127.2-3(2006):218-223. |
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来源:中国科学院大学
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