In situ synthesis of a three-dimensional supramolecular architecture from modified flexible ligand
文献类型:期刊论文
作者 | Li, Xiaoju; Cao, Rong; Guo, Zhengang; Wang, Yuling; Zhu, Xiandong |
刊名 | Journal of molecular structure
![]() |
出版日期 | 2006-10-23 |
卷号 | 798期号:1-3页码:64-68 |
关键词 | Copper Flexible ligand Hydrogen bonds X-ray diffraction |
ISSN号 | 0022-2860 |
DOI | 10.1016/j.molstruc.2006.03.050 |
通讯作者 | Cao, rong(rcao@ms.fjirsm.ac.cn) |
英文摘要 | A novel copper complex {[cu(l)(h2o)] center dot (h2o)(2)(no3)}(n) (1), (kl = potassium 4-(2-picolyl) piperidine-4-carboxylic acid) has been prepared from one-pot reaction of piperidine-4-carboxylic acid, 2-picolyl chloride hydrochloride and cu(no3)(2) center dot 3h(2)o in the presence of base. single-crystal x-ray diffraction analysis reveals that complex 1 consists of two-dimensional layers constructed from a new flexible multidentate ligand bridging dimeric unit. the l ligand adopts a chair configuration. the hydrogen bonding interactions extend the two-dimensional layers into a three-dimensional supramolecular architecture. [graphics] (c) 2006 elsevier b.v. all rights reserved. |
WOS关键词 | PIPERIDINE CARBOXYLIC-ACIDS ; METAL-ORGANIC FRAMEWORKS ; CRYSTAL-STRUCTURES ; COORDINATION POLYMERS ; COPPER(II) COMPLEXES ; ZINC(II) COMPLEXES ; CHAINS ; KINDS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
WOS记录号 | WOS:000241821900007 |
出版者 | ELSEVIER SCIENCE BV |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378481 |
专题 | 中国科学院大学 |
通讯作者 | Cao, Rong |
作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Xiaoju,Cao, Rong,Guo, Zhengang,et al. In situ synthesis of a three-dimensional supramolecular architecture from modified flexible ligand[J]. Journal of molecular structure,2006,798(1-3):64-68. |
APA | Li, Xiaoju,Cao, Rong,Guo, Zhengang,Wang, Yuling,&Zhu, Xiandong.(2006).In situ synthesis of a three-dimensional supramolecular architecture from modified flexible ligand.Journal of molecular structure,798(1-3),64-68. |
MLA | Li, Xiaoju,et al."In situ synthesis of a three-dimensional supramolecular architecture from modified flexible ligand".Journal of molecular structure 798.1-3(2006):64-68. |
入库方式: iSwitch采集
来源:中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。