Syntheses and crystal structures of two cyano-bridged bimetallic complexes [ce(dmso)(4)(h2o)(3)fe(cn)(6)]center dot h2o and [la(dmso)(4)(h2o)(3)co(cn)(6])center dot h2o (dmso = dimethylsulfoxide)
文献类型：期刊论文
| 作者 | Zhao Zhen-Qian; Chen Wen-Tong; Liu Xi; Cai Li-Zhen; Guo Guo-Cong; Huang Jin-Shun |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 25期号:12页码:1481-1486 |
| ISSN号 | 0254-5861 |
| 关键词 | Crystal structure Cyano-bridged bimetallic complex Hydrogen bond Lanthanide complex |
| 通讯作者 | Guo guo-cong(gcguo@ms.fjirsm.ac.cn) |
| 英文摘要 | Two new bimetallic cyano-bridged complexes [ce(dmso)(4)(h2o)(3)fe(cn)(6)]center dot h2o 1 and [la(dmso)(4)(h2o)(3)co(cn)(6)]center dot h2o 2 have been prepared by the ball milling reaction method and structurally characterized by x-ray single-crystal structure analyses. crystallographic data for 1: c14h32cefen6o8s4, m-r = 736.67, monoclinic, space group p2(1)/n, a = 14.952(1), b = 13.7276(9), c = 15.392(1) angstrom, beta = 108.288(1)degrees, v = 2999.6(4) angstrom(3), z = 4, d-c = 1.631 g/cm(3), mu = 2.304 mm(-1), f(000) = 1480, r = 0.0593 and wr = 0.1611; and those for 2: c14h32colan6o8s4, m-r = 73 8.54, monoclinic, space group p2(1)/n, a = 14.945(3), b = 13.731(3), c = 15.300(3) angstrom, beta = 107.806(1)degrees, v = 2989.3(11) angstrom(3), z = 4, d-c = 1.641 g/cm(3), mu = 2.288 mm(-1), f(000) = 1480, r = 0.0383 and wr = 0.1132. in both complexes the lanthanide ion is eight-coordinated in a square antiprism arrangement, and the fe(iii) or co(ii) ion in a nearly regular octahedral environment. the [lnm(cn)(6)(dmso)(4)(h2o)(3)]center dot h2o (ln = ce and m = fe for 1; ln = la and m = co for 2) species are held together via hydrogen bonds by coordinated water molecules, lattice water molecules and nitrogen atoms of cyanide groups to form a three-dimensional framework. |
| WOS关键词 | COORDINATION POLYMERS ; MAGNETISM |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| WOS记录号 | WOS:000243087800012 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378512 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Guo Guo-Cong |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao Zhen-Qian,Chen Wen-Tong,Liu Xi,et al. Syntheses and crystal structures of two cyano-bridged bimetallic complexes [ce(dmso)(4)(h2o)(3)fe(cn)(6)]center dot h2o and [la(dmso)(4)(h2o)(3)co(cn)(6])center dot h2o (dmso = dimethylsulfoxide)[J]. Chinese journal of structural chemistry,2006,25(12):1481-1486. |
| APA | Zhao Zhen-Qian,Chen Wen-Tong,Liu Xi,Cai Li-Zhen,Guo Guo-Cong,&Huang Jin-Shun.(2006).Syntheses and crystal structures of two cyano-bridged bimetallic complexes [ce(dmso)(4)(h2o)(3)fe(cn)(6)]center dot h2o and [la(dmso)(4)(h2o)(3)co(cn)(6])center dot h2o (dmso = dimethylsulfoxide).Chinese journal of structural chemistry,25(12),1481-1486. |
| MLA | Zhao Zhen-Qian,et al."Syntheses and crystal structures of two cyano-bridged bimetallic complexes [ce(dmso)(4)(h2o)(3)fe(cn)(6)]center dot h2o and [la(dmso)(4)(h2o)(3)co(cn)(6])center dot h2o (dmso = dimethylsulfoxide)".Chinese journal of structural chemistry 25.12(2006):1481-1486. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。