Protonation and rearrangement of the tricyclo[4.2.2.2(2,5)]dodeca-3,7,9,11-tetraene scaffold
文献类型：期刊论文
| 作者 | Cao, DR; Xu, SY; Gao, CM; Meier, H |
| 刊名 | Tetrahedron letters
 |
| 出版日期 | 2006-04-17 |
| 卷号 | 47期号:16页码:2759-2763 |
| 关键词 | Carbenium ions Hydrolysis Rearrangements Cyclic ketones |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2006.02.074 |
| 通讯作者 | Cao, dr(drcao@scut.edu.cn) |
| 英文摘要 | The biplanemers 2a,b contain enol ether substructures, which permit facile protonations of the pi electron system. the subsequent ether cleavage is characterized by rearrangements of the polycyclic scaffold of the carbenium ions or the electroneutral primary products. apart from the expected products 3a and 5a, a series of unexpected ketones and diketones (4a', 9b, 10b, 11b, and 12b) were obtained. (c) 2006 published by elsevier ltd. |
| WOS关键词 | CHARGE-TRANSFER ; ANTHRACENE ; PHOTOCYCLOADDITION ; PHOTODIMERIZATION ; NAPHTHALENES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000236438200023 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378552 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao, DR |
| 作者单位 | 1.S China Univ Technol, Coll Chem, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Chem, LCLC, Guangzhou 310650, Guangdong, Peoples R China 3.CAS, Grad Sch, Beijing 100039, Peoples R China 4.Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany |
| 推荐引用方式 GB/T 7714 | Cao, DR,Xu, SY,Gao, CM,et al. Protonation and rearrangement of the tricyclo[4.2.2.2(2,5)]dodeca-3,7,9,11-tetraene scaffold[J]. Tetrahedron letters,2006,47(16):2759-2763. |
| APA | Cao, DR,Xu, SY,Gao, CM,&Meier, H.(2006).Protonation and rearrangement of the tricyclo[4.2.2.2(2,5)]dodeca-3,7,9,11-tetraene scaffold.Tetrahedron letters,47(16),2759-2763. |
| MLA | Cao, DR,et al."Protonation and rearrangement of the tricyclo[4.2.2.2(2,5)]dodeca-3,7,9,11-tetraene scaffold".Tetrahedron letters 47.16(2006):2759-2763. |
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来源：中国科学院大学
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