Potassium gadolinium phosphate with a tunnel structure: synthesis, structure, and optical properties of k3gd5(po4)(6)
文献类型：期刊论文
| 作者 | Zhu, J; Cheng, WD; Wu, DS; Zhang, H; Gong, YJ; Tong, HN; Zhao, D |
| 刊名 | Crystal growth & design
 |
| 出版日期 | 2006-07-05 |
| 卷号 | 6期号:7页码:1649-1652 |
| ISSN号 | 1528-7483 |
| DOI | 10.1021/cg0601711 |
| 通讯作者 | Cheng, wd() |
| 英文摘要 | A potassium gadolinium phosphate crystal, k3gd5(po4)(6), has been synthesized by a high-temperature solution reaction and exhibits a new structural family of the alkali-metal-rare-earth phosphate system. single-crystal x-ray diffraction analysis shows the structure to be monoclinic with space group c2/c and the following cell parameters: a) 17.470(3) angstrom, b) 6.9365(6) angstrom, c = 18.096(2) angstrom, beta = 114.308(4)degrees, v = 1998.4( 5) angstrom(3), z = 4. its structure features a three-dimensional gd-5(po4)(6)(3-) anionic framework with interesting tunnels where the k atoms are located. the framework are constructed from gd polyhedra and isolated po4 tetrahedra. we have also investigated the optical properties of k3gd5(po4)(6) in terms of the measured absorption and emission spectra. |
| WOS关键词 | CRYSTAL-STRUCTURE ; TRANSITIONS ; SPECTRA ; GD3 |
| WOS研究方向 | Chemistry ; Crystallography ; Materials Science |
| WOS类目 | Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000238727700021 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378571 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cheng, WD |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Fujian 350002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, J,Cheng, WD,Wu, DS,et al. Potassium gadolinium phosphate with a tunnel structure: synthesis, structure, and optical properties of k3gd5(po4)(6)[J]. Crystal growth & design,2006,6(7):1649-1652. |
| APA | Zhu, J.,Cheng, WD.,Wu, DS.,Zhang, H.,Gong, YJ.,...&Zhao, D.(2006).Potassium gadolinium phosphate with a tunnel structure: synthesis, structure, and optical properties of k3gd5(po4)(6).Crystal growth & design,6(7),1649-1652. |
| MLA | Zhu, J,et al."Potassium gadolinium phosphate with a tunnel structure: synthesis, structure, and optical properties of k3gd5(po4)(6)".Crystal growth & design 6.7(2006):1649-1652. |
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来源：中国科学院大学
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