Aerobic oxidation of alcohols over Au/TiO2: An insight on the promotion effect of water on the catalytic activity of Au/TiO2
文献类型：期刊论文
| 作者 | Yang, Xiaomin1; Wang, Xiuna1; Liang, Changhai1; Su, Weiguang2; Wang, Chuang1; Feng, Zhaochi2; Li, Can; Qiu, Jieshan1 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2008-07-20 |
| 卷号 | 9期号:13页码:2278-2281 |
| 关键词 | Au/TiO2 water aerobic oxidation alcohol |
| 产权排序 | 1;1 |
| 通讯作者 | 邱介山 |
| 英文摘要 | the unique and significant promotion effect of water has been evidenced by the selective oxidation of benzyl alcohol to benzaldehyde over au/tio2 catalysts. water has dual promotional functions in the reaction system: to help form unique microdroplets in a multiphase reaction system and to assist the oxygen adsorption and activation. the conversion of benzyl alcohol at a molar ratio of water to solvent (p-xylene) of 7 is 7 times higher than in the absence of water. the present work has highlighted the potential of au/tio2 catalysts in aerobic oxidation of alcohols in the unique multiphase reaction system with water as promoting solvent. (c) 2008 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | preferential co oxidation ; selective oxidation ; gold nanoparticles ; supported gold ; carbon-monoxide ; hydrogenation ; temperature ; oxygen ; activation ; acetylene |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000257973600031 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/101249]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Ctr Nano Mat Sci, Carbon Res Lab, State Key Lab Fine Chem, Dalian 116012, Peoples R China 2.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xiaomin,Wang, Xiuna,Liang, Changhai,et al. Aerobic oxidation of alcohols over Au/TiO2: An insight on the promotion effect of water on the catalytic activity of Au/TiO2[J]. catalysis communications,2008,9(13):2278-2281. |
| APA | Yang, Xiaomin.,Wang, Xiuna.,Liang, Changhai.,Su, Weiguang.,Wang, Chuang.,...&Qiu, Jieshan.(2008).Aerobic oxidation of alcohols over Au/TiO2: An insight on the promotion effect of water on the catalytic activity of Au/TiO2.catalysis communications,9(13),2278-2281. |
| MLA | Yang, Xiaomin,et al."Aerobic oxidation of alcohols over Au/TiO2: An insight on the promotion effect of water on the catalytic activity of Au/TiO2".catalysis communications 9.13(2008):2278-2281. |
入库方式： OAI收割
来源：大连化学物理研究所
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