Melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) and its copolyester modified with rosin maleopimaric acid anhydride
文献类型：期刊论文
| 作者 | Liu, XQ; Li, CC; Zhang, D; Xiao, YN |
| 刊名 | Journal of polymer science part b-polymer physics
 |
| 出版日期 | 2006-03-15 |
| 卷号 | 44期号:6页码:900-913 |
| 关键词 | Crystallization kinetics Melting behaviors Poly(butylene succinate) Spherulitic morphologies |
| ISSN号 | 0887-6266 |
| DOI | 10.1002/polb.20758 |
| 通讯作者 | Li, cc() |
| 英文摘要 | This article investigated the melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) (pbs) and its copolyester (pbsr) modified with rosin maleopimaric acid anhydride, using wide-angle x-ray diffraction, differential scanning calorimeter (dsc), and polarized optical microscope. subsequent dsc scans of isothermally crystallized pbs and pbsr exhibited two melting endotherms, respectively, which was due to the melt-recrystallization process occurring during the dsc scans. the equilibrium melting point of pbsr (125.9 degrees c) was lower than that of pbs (139 degrees c). the commonly used avrami equation was used to describe the isothermal crystallization kinetics. for nonisothermal crystallization studies, the model combining avrami equation and ozawa equation was employed. the result showed a consistent trend in the crystallization process. the crystallization rate was decreased, the perfection of crystals was decreased, the recrystallization was reduced, and the spherulitic morphologies were changed when the huge hydrogenated phenanthrene ring was added into the chain of pbs. the activation energy (delta e) for the isothermal crystallization process determined by arrhenius method was 255.9 kj/mol for pbs and 345.7 kj/mol for pbsr. (c) 2006 wiley periodicals, inc. |
| WOS关键词 | DIFFERENTIAL SCANNING CALORIMETRY ; POLY(TETRAMETHYLENE SUCCINATE) ; POLY(ETHYLENE SUCCINATE) ; NONISOTHERMAL CRYSTALLIZATION ; ISOTHERMAL CRYSTALLIZATION ; DSC ; POLY(ETHYLENE-TEREPHTHALATE) ; DEGRADATION ; ADIPATE) ; CRYSTALS |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000235727500002 |
| 出版者 | JOHN WILEY & SONS INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378745 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, CC |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat,Ctr Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, XQ,Li, CC,Zhang, D,et al. Melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) and its copolyester modified with rosin maleopimaric acid anhydride[J]. Journal of polymer science part b-polymer physics,2006,44(6):900-913. |
| APA | Liu, XQ,Li, CC,Zhang, D,&Xiao, YN.(2006).Melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) and its copolyester modified with rosin maleopimaric acid anhydride.Journal of polymer science part b-polymer physics,44(6),900-913. |
| MLA | Liu, XQ,et al."Melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) and its copolyester modified with rosin maleopimaric acid anhydride".Journal of polymer science part b-polymer physics 44.6(2006):900-913. |
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来源：中国科学院大学
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