Novel catalytic systems containing n-busn(o)oh for the transesterification of dimethyl carbonate and phenol
文献类型：期刊论文
| 作者 | Du, ZP; Kang, WK; Cheng, T; Yao, J; Wang, GY |
| 刊名 | Journal of molecular catalysis a-chemical
 |
| 出版日期 | 2006-03-01 |
| 卷号 | 246期号:1-2页码:200-205 |
| 关键词 | N-butylstannonic acid Transesterification Dimethyl carbonate Cuprous iodide Promoting synthesis |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2005.10.030 |
| 通讯作者 | Wang, gy() |
| 英文摘要 | Novel catalytic systems containing n-butylstannonic acid (n-busn(o)oh) were used to synthesize methyl phenyl carbonate (mpc) and diphenyl carbonate (dpc) by the transesterification of dimethyl carbonate (dmc) with phenol in atmospheric conditions. the catalytic system consisting of n-busn(o)oh and cuprous iodide (cui) had the highest activity for the transesterification. when the reaction was carried out between 150 and 180 degrees c, with a molar ratio of n-busn(o)oh to cui of 1: 1, a catalyst amount 0.005 (molar ratio to dmc), a reaction time 10 h, a molar ratio of dmc to phenol of 2: 1, a dropping time of dmc 6 h, the conversion of phenol was 67.2%, and the selectivity of mpc and dpc was 40.2 and 59.6%, respectively. upon comparison of the activities of cu2o, cux (x = cl, br, 1) and the catalytic system being composed of n-busn(o)oh and cu2o/cux, it was found that cu2o and cux were excellent promoters, and the stronger was the anion electronegativity in the promoter, the weaker was the promoting catalysis of the promoter. (c) 2005 elsevier b.v. all rights reserved. |
| WOS关键词 | DIPHENYL CARBONATE ; DRUM ; MECHANISM ; CLUSTERS ; ACIDS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000236061800030 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378771 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, GY |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, ZP,Kang, WK,Cheng, T,et al. Novel catalytic systems containing n-busn(o)oh for the transesterification of dimethyl carbonate and phenol[J]. Journal of molecular catalysis a-chemical,2006,246(1-2):200-205. |
| APA | Du, ZP,Kang, WK,Cheng, T,Yao, J,&Wang, GY.(2006).Novel catalytic systems containing n-busn(o)oh for the transesterification of dimethyl carbonate and phenol.Journal of molecular catalysis a-chemical,246(1-2),200-205. |
| MLA | Du, ZP,et al."Novel catalytic systems containing n-busn(o)oh for the transesterification of dimethyl carbonate and phenol".Journal of molecular catalysis a-chemical 246.1-2(2006):200-205. |
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来源：中国科学院大学
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