Synthesis and characterization of high molecular weight metaloquinolate-containing polymers
文献类型：期刊论文
| 作者 | Mei, QB; Du, NY; Lu, MG |
| 刊名 | Journal of applied polymer science
 |
| 出版日期 | 2006-02-15 |
| 卷号 | 99期号:4页码:1945-1952 |
| 关键词 | 8-hydroxyquinoline Organic light-emitting diodes (oled) Synthesis Metaloquinolate-containing polymer Electroluminescent materials |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.22691 |
| 通讯作者 | Lu, mg() |
| 英文摘要 | In this article, a new method to synthesize novel metaloquinolate (alq(3), znq(2))-containing polymers is reported. a model polymer with 8-hydroxyquinoline ligands can be obtained by free-radical copolymerization with methyl methacrylate (mma), then metaloquinolate (alq(3), znq2)-containing polymers are prepared by coordinating reaction with di(8-hydroxyquinoline) aluminum (alq(3)) chelates or mono (8-hydroxyquinoline) zinc (znq) chelates without crosslinking. the structures of products are confirmed by nmr, ftir, ultra violet-visible, elementary analysis, photoluminescence spectrum, and gel permeation chromatography analysis. they are soluble in common solvents and suitable to form films. the use of alq(2) and znq avoided the crosslinking caused by the aiq3, znq2 formation between different polymer chains. different from the traditional small organic molecules in organic light-emitting diodes (oleds) fabrication, the polymer can be processed by spin coating without phase separation. compared to the pmma or mma-co-hema-ch2-hq, the t-8 of the metaloquinolate-containing polymers was much higher. it should be of interest for cled applications. (c) 2005 wiley periodicals, inc. |
| WOS关键词 | ALQ(3)-FUNCTIONALIZED POLYMERS ; ELECTROLUMINESCENCE ; COMPLEXES |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000234441200079 |
| 出版者 | JOHN WILEY & SONS INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378778 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Lu, MG |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Chem, Guangdong Key Lab Polymer Mat Elect, Guangzhou 510650, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mei, QB,Du, NY,Lu, MG. Synthesis and characterization of high molecular weight metaloquinolate-containing polymers[J]. Journal of applied polymer science,2006,99(4):1945-1952. |
| APA | Mei, QB,Du, NY,&Lu, MG.(2006).Synthesis and characterization of high molecular weight metaloquinolate-containing polymers.Journal of applied polymer science,99(4),1945-1952. |
| MLA | Mei, QB,et al."Synthesis and characterization of high molecular weight metaloquinolate-containing polymers".Journal of applied polymer science 99.4(2006):1945-1952. |
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来源：中国科学院大学
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