Preparation and characterization of langmuir-blodgett film of charge-transfer complex of 2-octadecyl-7,7,8,8-tetracyanoquinodimethane and 3,3 ',5,5 '-tetramethylbenzidine
文献类型：期刊论文
| 作者 | Wang, YB; Lu, F; Wei, PH; Xi, SQ; Wang, HS |
| 刊名 | Chemical journal of chinese universities-chinese
 |
| 出版日期 | 2006-05-10 |
| 卷号 | 27期号:5页码:935-938 |
| 关键词 | Charge-transfer complex Lb films Preparation method Structure |
| ISSN号 | 0251-0790 |
| 通讯作者 | Wang, hs() |
| 英文摘要 | Langmuir-blodgett(lb) films of the mixed-stack charge-transfer(ct) complex of 2-octadecyl-7, 7 8 8-tetracyanoquinodimethane(c(13)tcnq) and 3,3',5,5'-tetramethylbenzidine(tmb) were prepared. the structures, molecular orientation and morphology of tmb . c(18)tnq in lb films were characterized by infrared (ir), ultraviolet-visihic-near infrared (uv-vis-nir) spectroscopies and atomic force microscopy (afm). from the uy-vis-nir and ir spectra, it could be concluded that the tmb . c(18)tcnq complex is in a mixed-stacked arrangement style, and the chromophore planes of both c,tcnq and tmb are nearly perpendicular to the substrate surface. afm image shows,that the morphology of five-layer lb film of the complex consists of many two-dimensional hexagonal flake microcrystals. the width of these flake microcrystals is about 180 nm. |
| WOS关键词 | INFRARED SPECTROSCOPIES ; STRUCTURAL-CHARACTERIZATION ; MOLECULAR-ORIENTATION ; THERMAL-BEHAVIOR ; TEMPERATURE ; TRANSITION ; ACID |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000237792700035 |
| 出版者 | HIGHER EDUCATION PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378802 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, HS |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, YB,Lu, F,Wei, PH,et al. Preparation and characterization of langmuir-blodgett film of charge-transfer complex of 2-octadecyl-7,7,8,8-tetracyanoquinodimethane and 3,3 ',5,5 '-tetramethylbenzidine[J]. Chemical journal of chinese universities-chinese,2006,27(5):935-938. |
| APA | Wang, YB,Lu, F,Wei, PH,Xi, SQ,&Wang, HS.(2006).Preparation and characterization of langmuir-blodgett film of charge-transfer complex of 2-octadecyl-7,7,8,8-tetracyanoquinodimethane and 3,3 ',5,5 '-tetramethylbenzidine.Chemical journal of chinese universities-chinese,27(5),935-938. |
| MLA | Wang, YB,et al."Preparation and characterization of langmuir-blodgett film of charge-transfer complex of 2-octadecyl-7,7,8,8-tetracyanoquinodimethane and 3,3 ',5,5 '-tetramethylbenzidine".Chemical journal of chinese universities-chinese 27.5(2006):935-938. |
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来源：中国科学院大学
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