Nh4[bge3o8]: a new borogermanate framework made of infinite-chain building blocks
文献类型：期刊论文
| 作者 | Xiong, Ding-Bang; Chen, Hao-Hong; Li, Man-Rong; Yang, Xin-Xin; Zhao, Jing-Tai |
| 刊名 | Inorganic chemistry
 |
| 出版日期 | 2006-11-13 |
| 卷号 | 45期号:23页码:9301-9305 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/ic060967p |
| 通讯作者 | Zhao, jing-tai(jtzhao@mail.sic.ac.cn) |
| 英文摘要 | A new microporous borogermanate nh4[bge3o8] has been synthesized by a molten boric acid flux method with "reagent" quantities of water in which geo2, ethylenediamine, h2o, and h3bo3 (5:8:14:25) were heated together at 513 k for 4 days. the structure consists of {ge6o18}(n) chains, further linked together via bo4 tetrahedra, forming a three-dimensional open framework with intersecting channel systems including one-dimensional 10-membered-ring (mr) channels. interestingly, the infinite chains {ge6o18}(n) as building blocks, built of alternating 4- and 6-mrs made of vertex-sharing geo4 tetrahedra, construct the borogermanate framework. it is noteworthy that the high viscosity of the reactive medium and the quantity of water play important roles in the formation of the compound. |
| WOS关键词 | ACID FLUX SYNTHESIS ; CRYSTAL-STRUCTURE ; BORIC-ACID ; HYDROTHERMAL SYNTHESIS ; METAL-COMPLEXES ; BORATE POLYMER ; GERMANATE ; CHANNELS ; TOPOLOGY ; CLUSTER |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000241778900026 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378826 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhao, Jing-Tai |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, Ding-Bang,Chen, Hao-Hong,Li, Man-Rong,et al. Nh4[bge3o8]: a new borogermanate framework made of infinite-chain building blocks[J]. Inorganic chemistry,2006,45(23):9301-9305. |
| APA | Xiong, Ding-Bang,Chen, Hao-Hong,Li, Man-Rong,Yang, Xin-Xin,&Zhao, Jing-Tai.(2006).Nh4[bge3o8]: a new borogermanate framework made of infinite-chain building blocks.Inorganic chemistry,45(23),9301-9305. |
| MLA | Xiong, Ding-Bang,et al."Nh4[bge3o8]: a new borogermanate framework made of infinite-chain building blocks".Inorganic chemistry 45.23(2006):9301-9305. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。