Novel diethynylcarbazole macrocycles: synthesis and optoelectronic properties
文献类型:期刊论文
作者 | Zhao, Tianyue; Liu, Zhanxiang; Song, Yabin; Xu, Wei; Zhang, Deqing; Zhu, Daoben |
刊名 | Journal of organic chemistry
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出版日期 | 2006-09-15 |
卷号 | 71期号:19页码:7422-7432 |
ISSN号 | 0022-3263 |
DOI | 10.1021/jo0611869 |
通讯作者 | Xu, wei(wxu@iccas.ac.cn) |
英文摘要 | Diethynylcarbazole macrocycles 1b and 2b have been synthesized by oxidative coupling of appropriate precursors. in particular, macrocycle 2b was prepared by bimolecular pd-catalyzed oxidative coupling in 35% isolated yield. the spectroscopic properties of these macrocycles and their precursors were measured in detail. the films of these macrocycles by the dipping method and the langmuir-blodgett technique were fabricated to study their photoinduced charge-transfer properties. a rapid and steady cathodic photocurrent of these films was produced in a three-electrode cell when irradiated with white light. a possible mechanism of the photoinduced electron-transfer pathway was suggested. |
WOS关键词 | SHAPE-PERSISTENT MACROCYCLES ; PHOTOINDUCED ELECTRON-TRANSFER ; THIN-FILM TRANSISTORS ; ARYLENE ETHYNYLENE MACROCYCLES ; PORPHYRIN-FULLERENE DYADS ; SELF-ASSEMBLED MONOLAYERS ; LANGMUIR-BLODGETT-FILMS ; BIPYRIDINE DONOR SITES ; ION-SENSORY PROPERTIES ; X-RAY-STRUCTURE |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
WOS记录号 | WOS:000240371900034 |
出版者 | AMER CHEMICAL SOC |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378869 |
专题 | 中国科学院大学 |
通讯作者 | Xu, Wei |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Tianyue,Liu, Zhanxiang,Song, Yabin,et al. Novel diethynylcarbazole macrocycles: synthesis and optoelectronic properties[J]. Journal of organic chemistry,2006,71(19):7422-7432. |
APA | Zhao, Tianyue,Liu, Zhanxiang,Song, Yabin,Xu, Wei,Zhang, Deqing,&Zhu, Daoben.(2006).Novel diethynylcarbazole macrocycles: synthesis and optoelectronic properties.Journal of organic chemistry,71(19),7422-7432. |
MLA | Zhao, Tianyue,et al."Novel diethynylcarbazole macrocycles: synthesis and optoelectronic properties".Journal of organic chemistry 71.19(2006):7422-7432. |
入库方式: iSwitch采集
来源:中国科学院大学
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