中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Novel diethynylcarbazole macrocycles: synthesis and optoelectronic properties

文献类型:期刊论文

作者Zhao, Tianyue; Liu, Zhanxiang; Song, Yabin; Xu, Wei; Zhang, Deqing; Zhu, Daoben
刊名Journal of organic chemistry
出版日期2006-09-15
卷号71期号:19页码:7422-7432
ISSN号0022-3263
DOI10.1021/jo0611869
通讯作者Xu, wei(wxu@iccas.ac.cn)
英文摘要Diethynylcarbazole macrocycles 1b and 2b have been synthesized by oxidative coupling of appropriate precursors. in particular, macrocycle 2b was prepared by bimolecular pd-catalyzed oxidative coupling in 35% isolated yield. the spectroscopic properties of these macrocycles and their precursors were measured in detail. the films of these macrocycles by the dipping method and the langmuir-blodgett technique were fabricated to study their photoinduced charge-transfer properties. a rapid and steady cathodic photocurrent of these films was produced in a three-electrode cell when irradiated with white light. a possible mechanism of the photoinduced electron-transfer pathway was suggested.
WOS关键词SHAPE-PERSISTENT MACROCYCLES ; PHOTOINDUCED ELECTRON-TRANSFER ; THIN-FILM TRANSISTORS ; ARYLENE ETHYNYLENE MACROCYCLES ; PORPHYRIN-FULLERENE DYADS ; SELF-ASSEMBLED MONOLAYERS ; LANGMUIR-BLODGETT-FILMS ; BIPYRIDINE DONOR SITES ; ION-SENSORY PROPERTIES ; X-RAY-STRUCTURE
WOS研究方向Chemistry
WOS类目Chemistry, Organic
语种英语
WOS记录号WOS:000240371900034
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2378869
专题中国科学院大学
通讯作者Xu, Wei
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Tianyue,Liu, Zhanxiang,Song, Yabin,et al. Novel diethynylcarbazole macrocycles: synthesis and optoelectronic properties[J]. Journal of organic chemistry,2006,71(19):7422-7432.
APA Zhao, Tianyue,Liu, Zhanxiang,Song, Yabin,Xu, Wei,Zhang, Deqing,&Zhu, Daoben.(2006).Novel diethynylcarbazole macrocycles: synthesis and optoelectronic properties.Journal of organic chemistry,71(19),7422-7432.
MLA Zhao, Tianyue,et al."Novel diethynylcarbazole macrocycles: synthesis and optoelectronic properties".Journal of organic chemistry 71.19(2006):7422-7432.

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来源:中国科学院大学

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