Effect of calcium promoter on a precipitated iron-manganese catalyst for fischer-tropsch synthesis
文献类型：期刊论文
| 作者 | Tao, Zhichao; Yang, Yong; Zhang, Chenghua; Li, Tingzhen; Wang, Jianhua; Wan, Haijun; Xiang, Hongwei; Li, Yongwang |
| 刊名 | Catalysis communications
 |
| 出版日期 | 2006-12-01 |
| 卷号 | 7期号:12页码:1061-1066 |
| 关键词 | Ca promoter Fischer-tropsch synthesis Iron-manganese catalyst |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2006.05.009 |
| 通讯作者 | Li, yongwang(ywl@sxicc.ac.cn) |
| 英文摘要 | A series of precipitated fe/mn fischer-tropsch synthesis (fts) catalysts incorporated with calcium promoter were prepared by the combination of co-precipitation and spray-drying technology. the catalysts were characterized by using n-2 physisorption, co2 temperature-programmed desorption and mossbauer spectroscopy methods. fts performances of the catalysts were tested in a 1 dm(3) continuous stirred tank reactor. it is found that calcium-promoter has negligible effect on the textural properties, and the addition of calcium promoter can enhance the surface basicity of the catalyst. an appropriate amount of calcium promoter can promote the reduction and carburization of the catalysts during the reduction and fischer-tropsch synthesis (fts) reaction in syngas, but the excessive addition of calcium promoter will decrease the extent of reduction and carburization. the reaction results indicated that the activities of both fts and water-gas shift (wgs) decrease with the incorporation of calcium promoter. calcium promoter can inhibit the hydrogenation ability, suppress the formation of methane, and enhance the selectivities to olefin and higher molecular weight products. (c) 2006 elsevier b.v. all rights reserved. |
| WOS关键词 | MOSSBAUER-SPECTROSCOPY ; OXIDE CATALYSTS ; SELECTIVITY ; CARBON |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000242793800029 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378873 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, Yongwang |
| 作者单位 | 1.Chinese Acad Sci, State key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tao, Zhichao,Yang, Yong,Zhang, Chenghua,et al. Effect of calcium promoter on a precipitated iron-manganese catalyst for fischer-tropsch synthesis[J]. Catalysis communications,2006,7(12):1061-1066. |
| APA | Tao, Zhichao.,Yang, Yong.,Zhang, Chenghua.,Li, Tingzhen.,Wang, Jianhua.,...&Li, Yongwang.(2006).Effect of calcium promoter on a precipitated iron-manganese catalyst for fischer-tropsch synthesis.Catalysis communications,7(12),1061-1066. |
| MLA | Tao, Zhichao,et al."Effect of calcium promoter on a precipitated iron-manganese catalyst for fischer-tropsch synthesis".Catalysis communications 7.12(2006):1061-1066. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。