Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by titanocene complexes
文献类型：期刊论文
| 作者 | Niu Hong-Ying; Guo Hai-Ming; Yao Jie; Wang Yue; Wang Gong-Ying |
| 刊名 | Acta chimica sinica
 |
| 出版日期 | 2006-06-28 |
| 卷号 | 64期号:12页码:1269-1272 |
| 关键词 | Dimethyl carbonate Diphenyl carbonate Titanocene dichloride Titanocene complex Transesterification |
| ISSN号 | 0567-7351 |
| 通讯作者 | Wang gong-ying(gywang@cioc.ac.cn) |
| 英文摘要 | Titanocene dichloride cp2ticl2 was found to be a novel and efficient catalyst for the transesterification between dimethyl carbonate and phenol to produce diphenyl carbonate. cp2ticl2 is more stable in air and more convenient for industrial application than titanium esters. various titanocene complexes were used as catalysts for the transesterification on the basis of cp2ticl2. it was found that titanocene catalysts modified by various substituents would strongly influence the steric and electronic properties of the catalytic centers, the stability of the transition states, and their catalytic behaviors. when the substituent was smaller and more electron withdrawing, or the substituent could make the transition state more stable, the reaction would take place with better results. |
| WOS关键词 | MG |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000238662500012 |
| 出版者 | SCIENCE CHINA PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2378985 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang Gong-Ying |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453002, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Niu Hong-Ying,Guo Hai-Ming,Yao Jie,et al. Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by titanocene complexes[J]. Acta chimica sinica,2006,64(12):1269-1272. |
| APA | Niu Hong-Ying,Guo Hai-Ming,Yao Jie,Wang Yue,&Wang Gong-Ying.(2006).Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by titanocene complexes.Acta chimica sinica,64(12),1269-1272. |
| MLA | Niu Hong-Ying,et al."Transesterification of dimethyl carbonate and phenol to diphenyl carbonate catalyzed by titanocene complexes".Acta chimica sinica 64.12(2006):1269-1272. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。