Synthesis and properties of polythiophenes with conjugated side-chains containing carbon-carbon double and triple bonds
文献类型：期刊论文
| 作者 | Zhou, EJ; Hou, JH; Yang, CH; Li, YF |
| 刊名 | Journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2006-04-01 |
| 卷号 | 44期号:7页码:2206-2214 |
| 关键词 | Conjugated polymers Conjugated side-chain Grim method Synthesis Uv-vis absorption spectrum |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.21338 |
| 通讯作者 | Li, yf() |
| 英文摘要 | Two soluble side-chain conjugated polythiophenes, poly {3-[2-(4-octyloxyphenyl)-vinyl]-thiophene} (p3opvt) and poly{3-(4-octyloxy-phenylethynyl)-thiophene} (p3opet) have been synthesized successfully. in p3opvt and p3opet, substituted benzene rings are connected with the polythiophene backbone through trans carbon-carbon double bond and carbon-carbon triple bond, respectively. absorption spectra of the p3opvt and p3opet both show two absorption peaks located in uv and visible region, respectively. the results of optical and electrochemical measurements indicate that the conjugated side-chains can reduce the bandgap effectively. this type of side-chain conjugated polythiophenes may be promising for the applications in polymer photovoltaic cells and field effect transistors. (c) 2006 wiley periodicals, inc. |
| WOS关键词 | HYBRID SOLAR-CELLS ; REGIOREGULAR POLYTHIOPHENE ; SUBSTITUTED POLYTHIOPHENES ; GRIGNARD METATHESIS ; POLYMERS ; POLY(3-ALKYLTHIOPHENES) ; FUNCTIONALIZATION ; DERIVATIVES ; COPOLYMERS |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000236197800006 |
| 出版者 | JOHN WILEY & SONS INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379022 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, YF |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, EJ,Hou, JH,Yang, CH,et al. Synthesis and properties of polythiophenes with conjugated side-chains containing carbon-carbon double and triple bonds[J]. Journal of polymer science part a-polymer chemistry,2006,44(7):2206-2214. |
| APA | Zhou, EJ,Hou, JH,Yang, CH,&Li, YF.(2006).Synthesis and properties of polythiophenes with conjugated side-chains containing carbon-carbon double and triple bonds.Journal of polymer science part a-polymer chemistry,44(7),2206-2214. |
| MLA | Zhou, EJ,et al."Synthesis and properties of polythiophenes with conjugated side-chains containing carbon-carbon double and triple bonds".Journal of polymer science part a-polymer chemistry 44.7(2006):2206-2214. |
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来源：中国科学院大学
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