Adsorption of methanol on surface of zinc oxide
文献类型:期刊论文
作者 | Wang, MH; Dong, QN; Zhang, WY; Wei, W; Sun, YH |
刊名 | Chemical journal of chinese universities-chinese
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出版日期 | 2006-01-10 |
卷号 | 27期号:1页码:108-111 |
关键词 | Zno Methanol Water Ir spectrum Adsorption Pulse reaction |
ISSN号 | 0251-0790 |
通讯作者 | Sun, yh() |
英文摘要 | The adsorption of methanol on the surface of zinc oxide was investigated by in situ ftir and pulse reaction. the ftir results show that methoxyl group was formed from the adsorbed methanol on the surface of zinc oxide, and its amount increased with increasing adsorption temperature. further investigation indicates that methoxyl group was produced only by the reaction of methanol with surface hydroxyl group. it was also revealed that methoxyl group vanished quickly when it was exposed to water vapor. in the pulse reaction, water was detected while methanol was adsorbed on the the surface of zinc oxide, and then methanol was found while methoxy group contacted with water. thus, the reaction of methanol with hydroxy group on the surface of zinc oxide surface was reversible. |
WOS关键词 | SYNTHESIS GAS ; HYDROGENATION ; CU/ZNO/AL2O3 ; CATALYST |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000234815500029 |
出版者 | HIGHER EDUCATION PRESS |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379035 |
专题 | 中国科学院大学 |
通讯作者 | Sun, YH |
作者单位 | 1.Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, MH,Dong, QN,Zhang, WY,et al. Adsorption of methanol on surface of zinc oxide[J]. Chemical journal of chinese universities-chinese,2006,27(1):108-111. |
APA | Wang, MH,Dong, QN,Zhang, WY,Wei, W,&Sun, YH.(2006).Adsorption of methanol on surface of zinc oxide.Chemical journal of chinese universities-chinese,27(1),108-111. |
MLA | Wang, MH,et al."Adsorption of methanol on surface of zinc oxide".Chemical journal of chinese universities-chinese 27.1(2006):108-111. |
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来源:中国科学院大学
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