Asymmetric hydroformylation of olefins catalyzed by rhodium nanoparticles chirally stabilized with (R)-BINAP ligand
文献类型：期刊论文
| 作者 | Han, Difei1; Li, Xiaohong2; Zhang, Huidong1; Liu, Zhimin1; Hu, Gengshen1; Li, Can1 |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2008-03-18 |
| 卷号 | 283期号:1-2页码:15-22 |
| 关键词 | rhodium nanoparticles enantioselective hydroformylation chiral stabilization coordination phosphorus ligands |
| 产权排序 | 1;1 |
| 通讯作者 | 李灿 |
| 英文摘要 | rhodium nanoparticles have been conveniently synthesized by one-pot chemical reduction of aqueous rhodium chloride (rhcl3.3h(2)o) dispersed in toluene solution in the presence of amphiphilic tetraoctylammonium bromide (toab) and chiral (r)-binap at ambient conditions. the resulting highly dispersed rhodium nanoparticles show small and narrowly distributed core sizes (1.5-2.0 nm). the chirally stabilized rhodium nanoparticles were also immobilized on silica by impregnation to give the corresponding supported catalysts. p-31 mas nmr results and ir spectra of adsorbed co confirm that chiral (r)-binap ligands stabilize the nanoparticles by coordinative interaction between phosphine and rhodium, and produce chirally catalytic active sites on the rhodium nanocatalysts. chirally stabilized catalysts exhibit high regioselectivity and chiral induction ability for the asymmetric hydroformylation of olefins. the supported rhodium nanocatalysts show the increased activities compared to the unsupported catalysts (e.g. from 12 to 22 h(-1) for the hydroformylation of styrene). one hundred percentage regioselectivity of branched aldehyde and up to 59% ee were obtained for the hydroformylation of vinyl acetate. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | palladium nanoparticles ; gold nanoparticles ; chemistry ; phosphine ; hydrogenation ; colloids ; size |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000254748100003 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/101317]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Difei,Li, Xiaohong,Zhang, Huidong,et al. Asymmetric hydroformylation of olefins catalyzed by rhodium nanoparticles chirally stabilized with (R)-BINAP ligand[J]. journal of molecular catalysis a-chemical,2008,283(1-2):15-22. |
| APA | Han, Difei,Li, Xiaohong,Zhang, Huidong,Liu, Zhimin,Hu, Gengshen,&Li, Can.(2008).Asymmetric hydroformylation of olefins catalyzed by rhodium nanoparticles chirally stabilized with (R)-BINAP ligand.journal of molecular catalysis a-chemical,283(1-2),15-22. |
| MLA | Han, Difei,et al."Asymmetric hydroformylation of olefins catalyzed by rhodium nanoparticles chirally stabilized with (R)-BINAP ligand".journal of molecular catalysis a-chemical 283.1-2(2008):15-22. |
入库方式： OAI收割
来源：大连化学物理研究所
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