Synthesis, structure and luminescence property of two lanthanum phosphite hydrates: la-2(h2o)(x)(hpo3)(3) (x=1,2)
文献类型：期刊论文
| 作者 | Xiong, Ding-Bang; Li, Man-Rong; Liu, Wei; Chen, Hao-Hong; Yang, Xin-Xin; Zhao, Jing-Tai |
| 刊名 | Journal of solid state chemistry
 |
| 出版日期 | 2006-08-01 |
| 卷号 | 179期号:8页码:2571-2577 |
| 关键词 | Hydrothermal synthesis Crystal structure Lanthanum phosphite hydrate Luminescence property |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2006.04.035 |
| 通讯作者 | Zhao, jing-tai(jtzhao@mail.sic.ac.cn) |
| 英文摘要 | Two new lanthanum phosphite hydrates, la-2(h2o)(hpo3)(3) (1) and la-2(h2o)(2)(hpo3)(3) (2), were synthesized by a hydrothermal method. their crystal structures were determined by x-ray single-crystal method (1, monoclinic, c2/c (no. 15); a = 20.820(5) angstrom, b = 6.717(2) angstrom, c = 14.123(3) angstrom, beta = 101.261(3)degrees, v = 1937.0(8) angstrom(3); z = 8; 2, triclinic, p-1 (no. 2); a = 8.168(3) angstrom, b = 8.439(2) angstrom, c = 9.337(3) angstrom, alpha = 115.641(3)degrees, beta = 98.655(3)degrees, gamma = 105.124(3)degrees, v = 533.87(1)angstrom(3), z = 2). both crystal structures present three-dimensional open-framework structures containing channels, and i adopts intersecting type. in the two structures, the face-sharing dimers of laon (n = 8, 9) were observed. other characterizations by ir and tg-dsc were also described. furthermore, both the compounds doped with ce+3 showed intensive broad emission band around 340 nm under uv excitation. (c) 2006 elsevier inc. all rights reserved. |
| WOS关键词 | RAY-POWDER DIFFRACTION ; HYDROTHERMAL SYNTHESIS ; MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURES ; ZINC PHOSPHATE ; INDIUM PHOSPHATE ; ETHYLENEDIAMINE ; ZINCOPHOSPHITE ; COMPLEXES ; SOLIDS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000239639600040 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379093 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhao, Jing-Tai |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Cerma & Superfine, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, Ding-Bang,Li, Man-Rong,Liu, Wei,et al. Synthesis, structure and luminescence property of two lanthanum phosphite hydrates: la-2(h2o)(x)(hpo3)(3) (x=1,2)[J]. Journal of solid state chemistry,2006,179(8):2571-2577. |
| APA | Xiong, Ding-Bang,Li, Man-Rong,Liu, Wei,Chen, Hao-Hong,Yang, Xin-Xin,&Zhao, Jing-Tai.(2006).Synthesis, structure and luminescence property of two lanthanum phosphite hydrates: la-2(h2o)(x)(hpo3)(3) (x=1,2).Journal of solid state chemistry,179(8),2571-2577. |
| MLA | Xiong, Ding-Bang,et al."Synthesis, structure and luminescence property of two lanthanum phosphite hydrates: la-2(h2o)(x)(hpo3)(3) (x=1,2)".Journal of solid state chemistry 179.8(2006):2571-2577. |
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来源：中国科学院大学
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