Ir and raman investigation on the structure of (100-x)[0.33b(2)o(3)-0.67zno]-xv(2)o(5) glasses
文献类型：期刊论文
| 作者 | Li, Huaxin; Lin, Huixing; Chen, Wei; Luo, Lan |
| 刊名 | Journal of non-crystalline solids
 |
| 出版日期 | 2006-08-15 |
| 卷号 | 352期号:28-29页码:3069-3073 |
| 关键词 | Glasses Ftir measurements Raman spectroscopy Borates Structure Glass transition |
| ISSN号 | 0022-3093 |
| DOI | 10.1016/jjnoncrysol.2006.03.073 |
| 通讯作者 | Li, huaxin(lihuaxin@mail.sic.ac.cn) |
| 英文摘要 | Glasses with molar composition of (100-x)[0.33b(2)o(3)-0.67zno]-xv(2)o(5), x = 0, 5, 10, 15 and 20, were prepared, and the effect of v2o5 on the structure of the glass was investigated by ir and raman spectroscopy, tem and dta. this investigation shows that [bo3], [bo4] and [vo4] structural units are the predominant coordination polyhedra in the borovanadate glass. from the vanadium-free zinc borate glass, meta-, di-, pyro- and orthoborate groups were observed. adding v2o5 leads to the random substitution of [bo3] or [bo4] units in these borate groups by the [vo4] units, forming corresponding borovanadate groups. with increasing v2o5 content, the transition temperature of the glass decreases, that comes from the decrease of the interconnection of the structure units and the substitution of o-b-o by weaker o-v-o linkages. (c) 2006 elsevier b.v. all rights reserved. |
| WOS关键词 | MICROWAVE DIELECTRIC-PROPERTIES ; BORATE GLASSES ; SPECTROSCOPIC INVESTIGATIONS ; VIBRATIONAL-SPECTRUM ; BOROVANADATE GLASSES ; INFRARED-SPECTRA ; SYSTEM ; METAVANADATES ; SCATTERING ; CERAMICS |
| WOS研究方向 | Materials Science |
| WOS类目 | Materials Science, Ceramics ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000239375000019 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379122 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, Huaxin |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, Dept Glass Ceram, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Huaxin,Lin, Huixing,Chen, Wei,et al. Ir and raman investigation on the structure of (100-x)[0.33b(2)o(3)-0.67zno]-xv(2)o(5) glasses[J]. Journal of non-crystalline solids,2006,352(28-29):3069-3073. |
| APA | Li, Huaxin,Lin, Huixing,Chen, Wei,&Luo, Lan.(2006).Ir and raman investigation on the structure of (100-x)[0.33b(2)o(3)-0.67zno]-xv(2)o(5) glasses.Journal of non-crystalline solids,352(28-29),3069-3073. |
| MLA | Li, Huaxin,et al."Ir and raman investigation on the structure of (100-x)[0.33b(2)o(3)-0.67zno]-xv(2)o(5) glasses".Journal of non-crystalline solids 352.28-29(2006):3069-3073. |
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来源：中国科学院大学
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