Deactivation and reactivation of copper-containing pentatomic hydrotalcite in catalytic hydroxylation of phenol
文献类型：期刊论文
| 作者 | Chen, CX; Xu, CH; Feng, LR; Qiu, FL; Suo, JS |
| 刊名 | Journal of molecular catalysis a-chemical
 |
| 出版日期 | 2006-06-01 |
| 卷号 | 252期号:1-2页码:171-175 |
| 关键词 | Deactivation Pentatomic hydrotalcite Reactivation Phenol hydroxylation |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2006.01.065 |
| 通讯作者 | Chen, cx(ccx1759@163.com) |
| 英文摘要 | The phenol hydroxylation catalyzed over copper-containing pentatomic hydrotalcite (cu-phtl) is investigated during the catalyst cycle lifetime. the results show the fresh catalyst exhibits very high initial activity for the reaction. however, the rapid deactivation of catalyst is observed after the fifth operation. the cause of catalyst deactivation is discussed according to the characterizations of icp-aes, xrd, ft-ir, tem and xps, which is mainly attributed to carbon deposit on the surface of the catalyst. moreover, the deactivated catalyst is easily reactivated by burning deposited carbon in air and then washing with acetone, and the reactivated catalyst shows catalytic activity as almost high as the fresh sample. however, a small difference in catalytic activities between reactivated and fresh catalysts is possibly owing to the slight cu leaching. (c) 2006 elsevier b.v. all rights reserved. |
| WOS关键词 | TERNARY HYDROTALCITES ; REACTION-MECHANISM ; OXIDATION ; NI ; AL ; FE ; CR |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000237695400027 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379123 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, CX |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, CX,Xu, CH,Feng, LR,et al. Deactivation and reactivation of copper-containing pentatomic hydrotalcite in catalytic hydroxylation of phenol[J]. Journal of molecular catalysis a-chemical,2006,252(1-2):171-175. |
| APA | Chen, CX,Xu, CH,Feng, LR,Qiu, FL,&Suo, JS.(2006).Deactivation and reactivation of copper-containing pentatomic hydrotalcite in catalytic hydroxylation of phenol.Journal of molecular catalysis a-chemical,252(1-2),171-175. |
| MLA | Chen, CX,et al."Deactivation and reactivation of copper-containing pentatomic hydrotalcite in catalytic hydroxylation of phenol".Journal of molecular catalysis a-chemical 252.1-2(2006):171-175. |
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来源：中国科学院大学
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