Syntheses and characterizations of two palladium(ii) complexes of 5-mercapto-1-methyltetrazole
文献类型：期刊论文
| 作者 | Wang, YL; Shi, Q; Bi, WH; Li, X; Cao, R |
| 刊名 | Zeitschrift fur anorganische und allgemeine chemie
 |
| 出版日期 | 2006 |
| 卷号 | 632期号:1页码:167-171 |
| 关键词 | Palladium(ii) 5-mercapto-1-niethyltetrazolel 5-mercapto-1-methyltetrazolato Crystal structures |
| ISSN号 | 0044-2313 |
| DOI | 10.1002/zaac.200500342 |
| 通讯作者 | Cao, r() |
| 英文摘要 | Reaction of pdcl2(ch3cn)(2) with the sodium salt of 5-mercapto-1-methyltetrazole (metzsna) in methanol solution affords an interesting dinuclear palladium complex [pd-2(metzs)(4)] (1). however, treatment of pdcl2(ch3cn)(2) with neutral metzsh ligand in methanol solution produces a mononuclear palladium complex [pd(metzsh)(4)]cl-2 (2). both complexes were characterized by ir, (hnmr)-h-1, uv-vis spectroscopy as well as x-ray crystallography. single-crystal x-ray diffraction analyses of two complexes lead to the elucidation of the structures and show that i possesses an asymmetric structure: one pd atom is tetracoordinated by three sulfur atoms and one nitrogen atom to form pds3n coordination sphere, the other pd atom is tetracoordinated by three nitrogen atoms and one sulfur atom to form pdsn3 coordination sphere. the molecules of i are associated to i-d infinite linear chain by weak intermolecular (pds)-s-... contacts in the crystal lattice. in 2, the pd atom lies on an inversion center and has a square-planar coordination involving the s atoms from four metzsh ligands. the two chloride ions are not involved in coordination, but are engaged in hydrogen bonding. |
| WOS关键词 | CRYSTAL-STRUCTURE ; ELECTROCHEMICAL SYNTHESIS ; HETEROCYCLIC THIONES ; COORDINATION ; CHEMISTRY ; DONORS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000234002000025 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379187 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao, R |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, YL,Shi, Q,Bi, WH,et al. Syntheses and characterizations of two palladium(ii) complexes of 5-mercapto-1-methyltetrazole[J]. Zeitschrift fur anorganische und allgemeine chemie,2006,632(1):167-171. |
| APA | Wang, YL,Shi, Q,Bi, WH,Li, X,&Cao, R.(2006).Syntheses and characterizations of two palladium(ii) complexes of 5-mercapto-1-methyltetrazole.Zeitschrift fur anorganische und allgemeine chemie,632(1),167-171. |
| MLA | Wang, YL,et al."Syntheses and characterizations of two palladium(ii) complexes of 5-mercapto-1-methyltetrazole".Zeitschrift fur anorganische und allgemeine chemie 632.1(2006):167-171. |
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来源：中国科学院大学
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