L-prolinamide-catalyzed direct nitroso aldol reactions of alpha-branched aldehydes: a distinct regioselectivity from that with l-proline
文献类型:期刊论文
作者 | Guo, HM; Cheng, L; Cun, LF; Gong, LZ; Mi, AQ; Jiang, YZ |
刊名 | Chemical communications
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出版日期 | 2006-01-28 |
期号 | 4页码:429-431 |
ISSN号 | 1359-7345 |
DOI | 10.1039/b514194j |
通讯作者 | Gong, lz() |
英文摘要 | The first direct enantioselective n-nitroso aldol reaction of aldehyde with nitrosobenzene catalyzed by an l-prolinamide derivative is presented; the reactions proceed smoothly furnishing the a-hydroxyamino carbonyl compounds, the otherwise disfavored products, in good yields with up to 64% ee. |
WOS关键词 | CARBONYL-COMPOUNDS ; AMINOXYLATION ; KETONES ; AMINOOXYLATION ; OXIDATION ; 1,2-DIOLS ; ALCOHOLS ; ENAMINE ; HYDROXY ; ROUTE |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000235034800020 |
出版者 | ROYAL SOC CHEMISTRY |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379235 |
专题 | 中国科学院大学 |
通讯作者 | Gong, LZ |
作者单位 | 1.Chinese Acad Sci, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Union Lab Asymmetr Synth, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 3.Henan Normal Univ, Dept Chem, Xinxiang 453002, Henan, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, HM,Cheng, L,Cun, LF,et al. L-prolinamide-catalyzed direct nitroso aldol reactions of alpha-branched aldehydes: a distinct regioselectivity from that with l-proline[J]. Chemical communications,2006(4):429-431. |
APA | Guo, HM,Cheng, L,Cun, LF,Gong, LZ,Mi, AQ,&Jiang, YZ.(2006).L-prolinamide-catalyzed direct nitroso aldol reactions of alpha-branched aldehydes: a distinct regioselectivity from that with l-proline.Chemical communications(4),429-431. |
MLA | Guo, HM,et al."L-prolinamide-catalyzed direct nitroso aldol reactions of alpha-branched aldehydes: a distinct regioselectivity from that with l-proline".Chemical communications .4(2006):429-431. |
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来源:中国科学院大学
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