中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis, characterization and properties of poly(butylene succinate) reinforced by trimellitic imide units

文献类型:期刊论文

作者Liu, XQ; Li, CC; Zhang, D; Xiao, YN
刊名Macromolecular chemistry and physics
出版日期2006-04-03
卷号207期号:7页码:694-700
关键词Copolyester Mechanical properties Morphology Poly(butylene succinate) Thermal properties Trimellitic imide units
ISSN号1022-1352
DOI10.1002/macp.200500564
通讯作者Li, cc()
英文摘要A series of high molecular weight poly(butylene succinate) copolyester containing rigid imide units were synthesized in this paper. the chemical structure and composition of the copolyesters were determined by h-1 nmr spectroscopy and fourier transform infrared spectroscopy (ft-ir). gel permeation chromatography (gpc) was employed to determine the molecular weight and molecular weight distribution. the differential scanning calorimetry (dsc) technique showed that the melting temperature (t-m) of the copolyester decreased slightly with the increment in trimellitic imide unit content. when the imide unit content was increased to 6.3 mol-%, it had an elongation at break of 510% (83% higher than that of pbs) and a tensile strength of 37 mpa (7% higher than that of pbs). the changes in mechanical properties of the copolyester might be owed to the compositive effects of spherulitic morphology and imide units.
WOS关键词POLY(ETHYLENE ADIPATE) ; ALIPHATIC POLYESTERS ; THERMAL-DEGRADATION ; PHYSICAL-PROPERTIES ; BIODEGRADABILITY ; ACID ; COPOLYESTERS ; COPOLYMERS ; BLENDS ; DIOLS
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
WOS记录号WOS:000236806600005
出版者WILEY-V C H VERLAG GMBH
URI标识http://www.irgrid.ac.cn/handle/1471x/2379243
专题中国科学院大学
通讯作者Li, CC
作者单位1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Joint Lab Polymer Sci & Mat,Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Liu, XQ,Li, CC,Zhang, D,et al. Synthesis, characterization and properties of poly(butylene succinate) reinforced by trimellitic imide units[J]. Macromolecular chemistry and physics,2006,207(7):694-700.
APA Liu, XQ,Li, CC,Zhang, D,&Xiao, YN.(2006).Synthesis, characterization and properties of poly(butylene succinate) reinforced by trimellitic imide units.Macromolecular chemistry and physics,207(7),694-700.
MLA Liu, XQ,et al."Synthesis, characterization and properties of poly(butylene succinate) reinforced by trimellitic imide units".Macromolecular chemistry and physics 207.7(2006):694-700.

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来源:中国科学院大学

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