Construction of two novel 2d layer mo(w)/cu/s polymers using bidentate thiolato ligands as linkers
文献类型：期刊论文
| 作者 | Li, ZH; Du, SW; Wu, XT |
| 刊名 | Inorganic chemistry communications
 |
| 出版日期 | 2006 |
| 卷号 | 9期号:1页码:79-81 |
| 关键词 | Thiotungstate Thiomolybdate 2d layer structure Mo(w)/cu/s polymers Crystal structure Second-order nlo material |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2005.10.010 |
| 通讯作者 | Du, sw() |
| 英文摘要 | Reactions of thiomolybdate or thiotungstate [mos3](2-) (m = mo, w) with 3 equiv. of cus2p(ome)(2) led to the formation of two novel mo(w)/cu/s polymers [et4n][mos3cu3} {s2p(ome) (1, m = mo; 2, m = w). single-crystal x-ray diffraction studies reveal that 1 and 2 are the first examples that containing anionic 2d (6,3) net with nest-shaped [mos3cu3 (.) s2p(ome)(2)] clusters as 3-connecting nodes and tridentate [s2p(ome)(2)](-) ligands as linkers. both 1 and 2 crystallize in a noncentrosymmetric space group and the former polymer shows good second-order nlo performance. (c) 2005 elsevier b.v. all rights reserved. |
| WOS关键词 | NONLINEAR-OPTICAL PROPERTIES ; CRYSTAL-STRUCTURE ; STRUCTURAL-CHARACTERIZATION ; CHAIN POLYMER ; CLUSTER ; MO ; PZ |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000234520800022 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379301 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Du, SW |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, ZH,Du, SW,Wu, XT. Construction of two novel 2d layer mo(w)/cu/s polymers using bidentate thiolato ligands as linkers[J]. Inorganic chemistry communications,2006,9(1):79-81. |
| APA | Li, ZH,Du, SW,&Wu, XT.(2006).Construction of two novel 2d layer mo(w)/cu/s polymers using bidentate thiolato ligands as linkers.Inorganic chemistry communications,9(1),79-81. |
| MLA | Li, ZH,et al."Construction of two novel 2d layer mo(w)/cu/s polymers using bidentate thiolato ligands as linkers".Inorganic chemistry communications 9.1(2006):79-81. |
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来源：中国科学院大学
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